There are many diverse uses of accelerator mass spectrometry (AMS). 14 C studies at our laboratory include much research related to paleoclimate, with 14 C as a tracer of past changes in environmental conditions as observed in corals, marine sediments, and many terrestrial records. Terrestrial records can also show the influence of oceanic oscillations, whether they are short term, such as ENSO (El Niño/Southern Oscillation), or on the millennial time scale. In tracer applications, we have developed the use of 129 I as well as 14 C as tracers for nuclear pollution studies around radioactive waste dump sites, in collaboration with IAEA. We discuss some applications carried out in Tucson, AZ, for several of these fields and hope to give some idea of the breadth of these studies.KEY WORDS: accelerator mass spectrometry, carbon-14, paleoclimate, radiocarbon dating, beryllium-10, corals, forest fires, ENSO DOMAINS: environmental chemistry, freshwater systems, global systems, isotopes in the environment
INTRODUCTIONIn this paper, we describe our new accelerator mass spectrometry (AMS) system and also summarize some aspects of AMS applications at the University of Arizona facility. Over the last 2 decades, AMS has gradually evolved into the standard method of radionuclide measurements, especially for 1580 Jull et al.: Arizona: Geochronology of the Climatic Record TheScientificWorldJOURNAL (2002) 2, 1579-1593 radiocarbon. At the University of Arizona, we now operate two AMS machines. The first machine is a 2.
AMS RADIOCARBON MEASUREMENTS PretreatmentIt is important to consider the careful pretreatment of samples for radiocarbon dating, since improper cleaning can affect the results. Although basic procedures are uniform, pretreatment can vary between different radiocarbon laboratories. The processing of an AMS radiocarbon sample at Arizona follows several well-defined steps, which are summarized below for different types of samples:1. Organic materials such as charcoal, wood, cellulose, plant material, and animal tissue: after physical inspection, the samples are cleaned with 1 N HCl acid, 0.1% NaOH, and 1 N HCl (acid-base-acid [ABA] pretreatment), washed with distilled water, dried, and combusted at 900°C with CuO. 2. Carbonates: samples are etched with 100% H 3 PO 4 to remove 50 to 85% of the carbonate, dried, and hydrolyzed with H 3 PO 4 . An alternative is to use selective etching [3]. 3. Marine and lacustrine sediments: after cleansing in 1 N HCl and drying, the sample is combusted at 400°C in ~0.3 atm oxygen gas. We will discuss specific problems of sediment dating later in this paper. 4. Textiles, parchment, canvas, art works, and artifacts: the samples are given the ABA pretreatment and, after washing and drying, they are Soxhlet extracted with hexane, then ethanol, and finally methanol. After washing in distilled water and drying, they are combusted at 900°C with CuO[4]. 5. Ivory: samples are given a light acid pretreatment or a light ABA pretreatment. Dried samples are combusted at 900°C with CuO.Once the gr...