Environmentally friendly and non-polluting solvent pretreatment of palm samples for polyphenol analysis using choline chloride deep eutectic solvents

Fu, Najing; Lv, Runqiu; Guo, Zhi‐Xin; Guo, Yiwei; You, Xiaoyu; Tang, Boming; Han, Dandan; Yan, Hongyuan; Row, Kyung Ho

doi:10.1016/j.chroma.2017.02.036

Cited by 45 publications

(19 citation statements)

References 43 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…This review examined multiple research topics using DES in various methods to extract flavonoids from natural sources. All of the extraction methods agree upon the potential of DES in the extraction of plant sources, given the success of the extractions as well as the promising results in relation to conventional solvents, particularly so wherever a comparison could be directly drawn [9,10].…”

Section: Application Of Des On Flavonoid Extractionsmentioning

confidence: 63%

Deep Eutectic Solvents as Extraction Media for Valuable Flavonoids from Natural Sources

2019

View full text Add to dashboard Cite

The present review article attempts to summarize the use of deep eutectic solvents in the extraction of flavonoids, one of the most important classes of plant secondary metabolites. All of the applications reviewed have reported success in isolation and extraction of the target compounds; competitive, if not superior, extraction rates compared with conventional solvents; and satisfactory behavior of the extract in the latter applications (such as direct analysis, synthesis, or catalysis), wherever attempted.

show abstract

Section: Application Of Des On Flavonoid Extractionsmentioning

confidence: 63%

Deep Eutectic Solvents as Extraction Media for Valuable Flavonoids from Natural Sources

2019

View full text Add to dashboard Cite

show abstract

“…The search for environmentally friendly solvents that aims to reduce the negative effects of current existing state of the art solvents that are employed in chemical processes has been one of the top priorities of both industry and academia for a while . The main objective of the seek for “green” solvents is to facilitate the reduction in the use of hazardous and toxic organic based solvents that are used for various chemical processes and in recent years, the research on green chemistry has become progressively important in chemical sciences such as organic synthesis, inorganic materials preparation and analytical methods . Due to their negative effects on environment mitigation from the usage of traditional organic solvents such as methanol, dichloromethane, acetonitrile, hexane and acetone has been studied with the emphasis on the aspects of green chemistry and the exploration and application of green solvents has been receiving increasing attention …”

Section: Introductionmentioning

confidence: 99%

Gas Solubility and Rheological Behavior of Natural Deep Eutectic Solvents (NADES) via Combined Experimental and Molecular Simulation Techniques

et al. 2017

View full text Add to dashboard Cite

A potential of natural deep eutectic solvent (NADES) produced with the mixture of choline chloride with lactic acid, malic acid, citric acid and fructose is studied in this work. Experimental techniques are used to collect thermophysical property data including water content, thermal strength, density and gas solubility of CO2 and N2 data at pressures up to 50 bars. Detailed rheological measurements and various models have been studied to describe the dynamic flow behavior. Moreover, a density functional theory (DFT) and classical molecular dynamics (MD) methods have been used for investigating the physicochemical properties, structuring, dynamics and interfacial behavior of the studied NADES from the nanoscopic point of view to infer its viability for extensive usage. The rheological experimental results show usual shear‐thinning effect in which the η is decreasing with shear rate at all temperatures. A trend of studied NADES viscosity profiles were found as very similar to that of common ionic liquids that were previously, where the viscosities of all studied NADES decreased with increasing temperature. DFT simulations yielded with an accurate quantification of short‐range interaction but liquid state is also characterized by middle and long‐range interaction together with volumetric effects. Molecular orientations were quantified by radial distribution functions and the developed interactions are topologically characterized.

show abstract

“…Several papers focused on DESs-based extraction of polyphenols, especially flavonoids and phenolic acids from plants, such as Dictamnus albus, Foeniculum vulgare, Origanum majorana, mint, Salvia officinalis [20], Platycladi Cacumen [15], Sophora japonica [21], and others [4,5]. Duan et al [22] [23] investigated the extraction of protocatechuic acid, catechins, epicatechin and caffeic acid from Trachycarpus fortune using DESs as the extraction medium. In order to prepare the DESs, ChCl was mixed with ethylene glycol, glycerol, xylitol, phenol, formic acid, citric acid, oxalic acid and malonic acid.…”

Section: Extraction By Deep Eutectic Solventsmentioning

confidence: 99%

“…Being environmentally friendly, with low vapor pressure, non-flammability and good thermal stability, DESs proved their high potential for the extraction and purification of polyphenols. The highest extraction yield of protocatechuic acid and epicatechin was achieved using a mixture of ChCl and formic acid in a 1:1 molar ratio at the extraction temperature of 40 • C in a 6-h procedure [23]. Jeong et al [24] tested 26 DESs, including 9 betaine-based DESs, 8 containing citric acid and 9 containing glycerols, in the process of extraction of catechin from green tea Camellia sinensis.…”

Section: Extraction By Deep Eutectic Solventsmentioning

confidence: 99%

Involvement of Deep Eutectic Solvents in Extraction by Molecularly Imprinted Polymers—A Minireview

et al. 2020

View full text Add to dashboard Cite

Substantial research activity has been focused on new modes of extraction and refining processes during the last decades. In this field, coverage of the recovery of bioactive compounds and the role of green solvents such as deep eutectic solvents (DESs) also gradually increases. A specific field of DESs involvement is represented by molecularly imprinted polymers (MIPs). The current state and prospects of implementing DESs in MIPs chemistry are, based on the accumulated experimental data so far, evaluated and discussed in this minireview.

show abstract

Environmentally friendly and non-polluting solvent pretreatment of palm samples for polyphenol analysis using choline chloride deep eutectic solvents

Cited by 45 publications

References 43 publications

Deep Eutectic Solvents as Extraction Media for Valuable Flavonoids from Natural Sources

Deep Eutectic Solvents as Extraction Media for Valuable Flavonoids from Natural Sources

Gas Solubility and Rheological Behavior of Natural Deep Eutectic Solvents (NADES) via Combined Experimental and Molecular Simulation Techniques

Involvement of Deep Eutectic Solvents in Extraction by Molecularly Imprinted Polymers—A Minireview

Contact Info

Product

Resources

About