Enzyme-inspired catalysts with high activity and selectivity for oxidative polymerization of 2-phenylphenol

Nakano, Akiyuki; Raut, Vivek S.; Asao, Naoki; Ando, Akane; Fujisawa, Kiyoshi; Higashimura, Hideyuki

doi:10.1039/d3cy00170a

Catal. Sci. Technol.

2023

DOI: 10.1039/d3cy00170a

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Enzyme-inspired catalysts with high activity and selectivity for oxidative polymerization of 2-phenylphenol

Akiyuki Nakano

Vivek S. Raut

Naoki Asao

et al.

Abstract: Enzyme-inspired copper catalysts having the 1,4,7-triazacyclonones substituted at the nitrogen atoms with tBu group(s) have been developed for the regioselective oxidative polymerization of 2-phenylphenol. These in situ prepared catalysts remarkably...

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2024

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Enzyme model-catalyzed oxidative polymerization of 5-cyano-2-methoxyphenol, a new phenolic monomer with cyano substituent

Takechi,

Oshima,

Nakano

et al. 2024

Chemistry Letters

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Oxidative polymerization of 5-cyano-2-methoxyphenol was achieved with high C–O coupling selectivity by an enzyme model-catalyst as the first example of a cyano-substituted phenol. The electron-withdrawing/donating interaction of the substituents would lead to the high reactivity and selectivity. Surprisingly, the resulting polymer showed a very narrow molecular weight distribution. The polymer consisted of a linear unit with small amounts of branched and bent units, in which C = O structure was slightly detected but could be reduced by lowering the reaction temperature.

show abstract

Enzyme model-catalyzed oxidative polymerization of 5-cyano-2-methoxyphenol, a new phenolic monomer with cyano substituent

Takechi,

Oshima,

Nakano

et al. 2024

Chemistry Letters

View full text Add to dashboard Cite

show abstract

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Enzyme-inspired catalysts with high activity and selectivity for oxidative polymerization of 2-phenylphenol

Abstract: Enzyme-inspired copper catalysts having the 1,4,7-triazacyclonones substituted at the nitrogen atoms with tBu group(s) have been developed for the regioselective oxidative polymerization of 2-phenylphenol. These in situ prepared catalysts remarkably...

Cited by 1 publication

References 30 publications

Enzyme model-catalyzed oxidative polymerization of 5-cyano-2-methoxyphenol, a new phenolic monomer with cyano substituent

Enzyme model-catalyzed oxidative polymerization of 5-cyano-2-methoxyphenol, a new phenolic monomer with cyano substituent

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