“…This is attested to by the X‐ray crystal structures of 1 – 4 . The vibrations at 1665 cm –1 for 1 , 1660 cm –1 for 3 , and 1667 cm –1 for 4 are characteristic of the guanidinium cation28 and correspond to ν(C–N) vibrations, whereas the bands observed at 1549, 846, and 716 cm –1 for 4 have been assigned to 1,10‐phenanthroline stretches 29,30. Furthermore, ν(Zr–O) vibrations are present at 522 cm –1 for 1 , 507 cm –1 for 2 , 521 cm –1 for 3 , and 509 cm –1 for 4 ,31,32 whereas the bands observed at 691 cm –1 for 1 and 705 cm –1 for 2 have been assigned to ν(Zr–F) vibrations 33.…”