Abstract:Graphical Abstract:Polymer coupling reactions are some of the most challenging chemical transformations due to low end-group concentration, steric hindrance, and decreased reactivity. Thiolyne chemistry is shown to be a near-quantitative and selective strategy for the coupling of preformed polymers to give block and graft copolymers. With aromatic alkynes under a wide range of conditions, specific monoaddition is achieved with efficiencies surpassing those of traditional thiol-ene chemistry.This text was incor… Show more
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