This study was performed in the Linshui River Watershed to explore the contents of heavy metals in river water, their species, and health risks. The test results show that the contents of arsenic (As), chromium (Cr), copper (Cu), uranium (U), and thorium (Th) are relatively low and below the limit of class III of the environmental quality standards for surface water. According to the analysis through PHREEQC (version 2.18), the main species of As, Cr, Cu, U, and Th are H