A theoretical model of silicon solar cells with ultra-small textured surface has been established based on depletion approximation and drift diffusion theory. The ultra-small textured surface achieves the low reflectance by multiple reflections among the silicon nanowires (NWs). The electrical performances of the solar cells, including open circuit voltage (V oc ), short circuit current (I sc ) and conversion efficiency ( ), are analyzed by the theoretical model. The results show that the low reflectance is not the only pursuit in manufacturing the Si NWs solar cells. Other factors including optimizing the surface passivation, improving the silicon wafers quality and designing the proper nanowire length should be considered together with NWs structure.
ultra-small textured surface, solar cell, electrical properties
Citation:Li H F, Jia R, Ding W C, et al. The analysis of electrical performances of nanowires silicon solar cells.Owing to the energy crisis and air pollution, making use of solar energy has attracted more and more attention [1][2][3][4].The solar cell with ultra-small textured surface also known as nanowires (NWs) solar cell has received great attention recently [5,6]. Based on the relationship between the built-in electric field direction and the incident light direction, the NWs solar cells can be divided into two categories: planar pn junction structure [7] in which the built-in electric field direction is parallel to the incident light direction, as shown in Figures 1(b) and (d); the radial pn junction structure [8] in which the two directions are perpendicular. The NWs solar cell with planar pn junction structure (for convenience, in the following "NWs solar cell with planar pn junction structure" is referred to as "NWs solar cell") has many specialties such as low reflectance, low production cost and compatibility with existing solar cell production process. According to the released reports, the reflectance of the NWs solar cell can reach 3% to 5% [9], lower 30% to 40% than that of the conventional solar cells. However, most of the reports are dedicated to the low reflectance but without concerning the performance of the NWs solar cell [10].In this paper, a theoretical model is established. The electrical properties including V oc , I sc , and are analyzed by this model.
Model foundationTo simplify the calculation, the model makes the following assumptions. The first assumption is the depletion approximation: the electric field vanishes at a fixed distance from either side of the junction, leaving quasi-neutral p and n type regions. Within these quasi-neutral regions, the majority carriers have their equilibrium value and only the variation in the minority carrier density determines the current. The second one is that the recombination rate in the neutral region is approximately linear with the minority carrier density.