Evaluation Model of Hard Limestone Reformation and Strength Weakening Based on Acidic Effect

Abstract

The typical thick-hard limestone roof with high failure pressure and easy fracture closure under in situ stress is extremely prone to induce disasters, which seriously threatens the safe production of coal mines. The modification of carbonate minerals by acidic effects can effectively realize the weakening control of hard limestone strata. In this study, a multi-factor orthogonal experiment was designed for limestone acidification reactions, and the evaluation model for the reformation and strength weakening of hard limestone based on the acidic effect was established accordingly. The results showed that there is an order in the influence of various factors on the reaction parameters and strength indices of acidified limestone, and the improvement of rock properties by the level difference of acid concentration is significantly better than that of acid type and acidification time. Through numerical analysis, the evaluation model of limestone reformation and strength weakening considering the acid reaction parameters is given. The reliability of the model passed the credibility test and experimental verification, which can effectively reflect the strength response characteristics of acidified limestone. The simulated annealing (SA) algorithm is introduced to derive the optimal acidification system suitable for limestone weakening. Combined with the model, the control mechanism of the acidic effect on hard limestone strata was analyzed. The acidic effect can not only induce the rapid generation and expansion of micro-cracks at mineral-containing crystal defects, but also make the cracks remain relatively open under in situ stress due to the differential interaction on mineral components, which is conducive to the bearing capacity reduction and structural damage of limestone rock mass. The research results provide theoretical guidance for the acidification control of hard limestone strata in underground mines.

Effect of freez thaw on the solubility the Mesozoic limestone (a case study: Iran, Dorfak karstic area, Guilan province, North of Iran)

“…The solubility value of carbonate rocks has been studied by various researchers all over the world. Including: Ajalloeian, et al, (2001);Ghobadi, (2005); Heidari, et al, (2011);Taheri, et al, (2016); Mousavi-Maddah, et al, (2020);Taheri, et al, (2021); Mohammadian, et al, (2021); Gessert and Hochmuth, (2022);Chen, et al, (2023);Hou, et al, (2023).…”