Evaluation of CO2 separation performance with enhanced features of materials – Pebax® 2533 mixed matrix membranes containing ZIF-8-PEI@[P(3)HIm][Tf2N]

Li, Guoqiang; Kujawski, Wojciech; Tonkonogovas, Andrius; Knozowska, Katarzyna; Kujawa, Joanna; Olewnik-Kruszkowska, Ewa; Pedišius, Nerijus; Stankevičius, Arūnas

doi:10.1016/j.cherd.2022.03.023

Cited by 24 publications

(15 citation statements)

References 60 publications

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“…The use of nanoparticles such as carboxylated carbon nanotubes (CNTs) composite prevented the aggregation of ZIF-8 in the membrane, increased the free volume of the MMM, and enhanced the CO2 adsorption performance and CO2/N2 separation performance [160] . ZIF-8-PEI@IL (15 wt.%) increased the CO2 permeability of MMMs by 123%, and the selectivity of CO2/N2 and CO2/CH4 from 17 and 12 to 76 and 25, respectively [161] .…”

Section: Effect Of Zifs' Properties: Structure Porosity Guest Molecul...mentioning

confidence: 99%

“…Several polymers and their blend were reported, including polyether-block-amide (PEBA2533) polymer [159] , Pebax-1657 [160] , Pebax ® 2533 [161] , Matrimid ® [162] , polysulfone [163] , and Matrimid ® /polysulfone blend [164] . Polymer and inorganic supports were also reported for poly(vinyl chloride)-poly(oxyethylene methacrylate) (PVC-POEM)/alumina [165] .…”

Section: 2zifs-based Membranementioning

confidence: 99%

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A Review on Removal of Carbon Dioxide (CO2) using Zeolitic Imidazolate Frameworks: Adsorption and Conversion via Catalysis

Abdelhamid

2022

Preprint

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Carbon dioxide (CO2) is one of the culprit causes of global climatic changes. Furthermore, the efficient separation of CO2 from other gaseous mixtures using ZIFs-based materials is vital for several processes such as flue gas separation, gas sweetening, and natural gas processing. Zeolitic imidazolate frameworks (ZIFs)-based materials are emerging adsorbents and catalysts for CO2 gas removal via adsorption and conversion into valuable chemicals. ZIFs-based adsorbents with high adsorption/conversion efficiencies and tunable properties can be achieved by judicious synthesis and fabrication methods. We reviewed ZIF-based materials for CO2 removal via adsorption and catalysis (e.g., cycloaddition, carboxylation, hydrogenation, N-formylation, electrocatalysis, and photocatalysis). In addition, recent development methods such as membrane synthesis and ways to improve the gas separation performance of ZIF membranes were highlighted. The prospective point of view to promote industrial applications and commercialization of ZIF-based materials was briefly discussed. Once challenges such as low performance and reproducibility for ZIFs-based materials are solved, scalability and cost-effectiveness should not become issues.

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Section: Effect Of Zifs' Properties: Structure Porosity Guest Molecul...mentioning

confidence: 99%

Section: 2zifs-based Membranementioning

confidence: 99%

A Review on Removal of Carbon Dioxide (CO2) using Zeolitic Imidazolate Frameworks: Adsorption and Conversion via Catalysis

Abdelhamid

2022

Preprint

View full text Add to dashboard Cite

show abstract

“…[177] ZIF-8-PEI@IL (15 wt.%) increased the CO 2 permeability of MMMs by 123%, and the selectivity of CO 2 /N 2 and CO 2 /CH 4 from 17 and 12 to 76 and 25, respectively. [178] The morphology of ZIF materials exhibits an insignificant effect on CO 2 adsorption. [179] The low and high aspect ratio ZIF-78 showed similar CO 2 adsorption behavior.…”

Section: Zif-based Membranementioning

confidence: 99%

“…ZIF‐8 loading of 10 wt.% using cross‐linked PEGDA increased the permeability of CO 2 from 130 to 320 Barrer, that is, 170% increment without any observation for the reduction of the selectivity of CO 2 adsorption. [ 166 ] Several polymers and their blend were reported, including polyether‐block‐amide (PEBA2533) polymer, [ 167 ] Pebax‐1657, [ 177 ] Pebax® 2533, [ 178 ] Matrimid®, [ 179 ] polysulfone, [ 180 ] and Matrimid®/polysulfone blend. [ 168 ] Polymer and inorganic supports were also reported for poly(vinyl chloride)‐poly(oxyethylene methacrylate) (PVC‐POEM)/alumina.…”

Section: Adsorption Of Co2mentioning

confidence: 99%

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Removal of carbon dioxide using zeolitic imidazolate frameworks: Adsorption and conversion via catalysis

Abdelhamid

2022

Applied Organom Chemis

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Carbon dioxide (CO2) is one of the culprit causes of global climatic changes. Furthermore, the efficient separation of CO2 from other gaseous mixtures using zeolitic imidazolate framework (ZIF)‐based materials is vital for several processes such as flue gas separation, gas sweetening, and natural gas processing. ZIF‐based materials are emerging adsorbents and catalysts for CO2 gas removal via adsorption and conversion into valuable chemicals. ZIF‐based adsorbents with high‐adsorption/conversion efficiencies and tunable properties can be achieved by judicious synthesis and fabrication methods. We reviewed ZIF‐based materials for CO2 removal via adsorption and catalysis (e.g., cycloaddition, carboxylation, hydrogenation, N‐formylation, electrocatalysis, and photocatalysis). In addition, recent development methods such as membrane technologies and ways to improve the gas separation performance of ZIF membranes were highlighted. The prospective point of view to promote industrial applications and commercialization of ZIF‐based materials was briefly discussed. Once challenges such as low performance and reproducibility for ZIF‐based materials are solved, scalability and cost‐effectiveness should not become issues.

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Effect of poly(ether block amide)‐graphene/ZnO membranes in mixed gas separation performance

Mendoza‐Mendoza

España‐Sánchez

Montes‐Luna

et al. 2022

J of Applied Polymer Sci

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Evaluation of CO2 separation performance with enhanced features of materials – Pebax® 2533 mixed matrix membranes containing ZIF-8-PEI@[P(3)HIm][Tf2N]

Cited by 24 publications

References 60 publications

A Review on Removal of Carbon Dioxide (CO2) using Zeolitic Imidazolate Frameworks: Adsorption and Conversion via Catalysis

A Review on Removal of Carbon Dioxide (CO2) using Zeolitic Imidazolate Frameworks: Adsorption and Conversion via Catalysis

Removal of carbon dioxide using zeolitic imidazolate frameworks: Adsorption and conversion via catalysis

Effect of poly(ether block amide)‐graphene/ZnO membranes in mixed gas separation performance

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