The flexural behaviour and elastic rebound are the main parameters that determine the global performance of a ski boot during skiing. These two parameters are related to the visco-elastic properties of the polymeric materials used. For this reason, the visco-elastic properties of the materials most utilized for the production of ski boots (polyurethanes and polyolefins) have been studied using dynamic mechanical thermal analysis in a temperature range between 230°C and + 50°C. Also, the flexural and rebound behaviours of the boot have also been tested using specially designed test benches. The dynamic mechanical thermal analysis results and the flexural and rebound tests results were compared, and a significant effect of the visco-elastic properties on the flexural and rebound behaviour of ski boots was seen. Therefore, dynamic mechanical thermal analysis can be used in a knowledge-based design process of new ski boots in order to improve on-snow performances.