The use of geopolymer in pavement constructions is strongly encouraged. Many studies have demonstrated the vast potential of using industrial-by-products-based geopolymers. This paper discusses the modification of asphalt binders with geopolymers, namely geopolymer-modified asphalt (GMA) and geopolymer-modified asphalt mixture (GMAM). In addition, curing geopolymer materials, engineering properties, production techniques, and prospective utilisation in the pavement construction, such as durability and sustainability, are also discussed. The literature review showed that many industrial by-products, including red mud, blast furnace slag, fly ash, and mine waste, are used to produce geopolymers because of the metal components such as silicon and aluminium in these materials. The geopolymers from these materials influence the rheological and physical properties of asphalt binders. Geopolymers can enhance asphalt mixture performance, such as stability, fatigue, rutting, and low-temperature cracking. The use of geopolymers in asphalt pavement has beneficial impacts on sustainability and economic and environmental benefits.