2022
DOI: 10.1055/a-1755-3090
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Evolution of a Reagent-Controlled Strategy for β-Selective C-Glycoside Synthesis

Abstract: C-alkyl glycosides represent an attractive class of non-hydrolyzable carbohydrate mimetics which possess enormous potential as next-generation therapeutics. Methods for the direct stereoselective synthesis of C-alkyl glycosides with a broad substrate tolerance are limited, however. This is especially in the case of β-linked C-alkyl glycosides, where direct methods for synthesis from commonly available coupling partners remain limited. This account describes the evolution of our laboratory’s studies on glyco… Show more

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