Metal oxides are useful materials that have various applications in advanced field such as, in view of their different properties, hardness, thermal dependability and compound resistance. Novel utilizations of the nanostructures of these oxides are drawing in critical enthusiasm as new preparation process are created and new structures are described. Hydrothermal synthesis is a fruitful procedure to prepare different sensitive structures of metal oxides on the scales from a couple to several nanometres, particularly, the hugely scattered middle structures which are hardly through pyropreparation.Titanium dioxide nanocrystals are synthesis by a hydrolysis procedure of metatitanic acid. Nano precious crystal of different sizes is procure in the after calcinations from 150 to 225 o C. Raman scattering was utilized to examine the advancement of the anatase stage in the nano crystal during calcinations.