We consider the Chiral Cosmological Models (CCMs) and modified gravity theories associated with them. Generalization of the superpotential method for a general CCM with several scalar fields is performed, and the method of construction CCMs admitting exact solutions is developed. New classes of exact solutions in the two-component CCM connected with an f (R) gravity model with an additional scalar field have been constructed. We construct new cosmological solutions for a diagonal metric of the target space, including modified power-law solutions. In particular, we propose the reconstruction procedure based on the superpotential method and present examples of kinetic part reconstruction for periodic and hyperbolic Hubble parameters. We also focus on a cyclic type of Universe dubbed the Quasi-Steady State (QSS) model, with the aim of constructing single-and double-field potentials for one and the same behaviour of the Hubble parameter using the developed superpotential method for the CCM. The realization of this task includes a new set of solutions for a CCM with a scale factor characterized by the QSS theory. We also propose a method for reducing the two-field CCM to the single scalar field model.