Expanding the cryogenic electron microscopy toolbox to reveal diverse classes of battery solid electrolyte interphase

Mecklenberg, Matthew; Yuan, Xintong; Wang, Chongzhen; Liu, Bo; Li, Yuzhang

doi:10.1016/j.isci.2022.105689

Cited by 11 publications

(6 citation statements)

References 59 publications

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“…iDPC improves contrast and image quality, particularly in the context of the light elements that are prevalent in battery materials. 66 This technique is essential for unraveling the intricate details of material degradation and SEI layer formation, 67 which are critical factors in battery performance and longevity. Meanwhile, 4D-STEM is emerging as a transformative approach to studying structural and electric field distributions at the nanoscale.…”

Section: Enhanced Elp-tem For Battery Reactionsmentioning

confidence: 99%

Advances in Electrochemical Liquid-Phase Transmission Electron Microscopy for Visualizing Rechargeable Battery Reactions

Hu,

Yang,

Zeng

2024

ACS Nano

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This review presents an overview of the application of electrochemical liquid-phase transmission electron microscopy (ELP-TEM) in visualizing rechargeable battery reactions. The technique provides atomic-scale spatial resolution and real-time temporal resolution, enabling direct observation and analysis of battery materials and processes under realistic working conditions. The review highlights key findings and insights obtained by ELP-TEM on the electrochemical reaction mechanisms and discusses the current limitations and future prospects of ELP-TEM, including improvements in spatial and temporal resolution and the expansion of the scope of materials and systems that can be studied. Furthermore, the review underscores the critical role of ELP-TEM in understanding and optimizing the design and fabrication of high-performance, long-lasting rechargeable batteries.

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Section: Enhanced Elp-tem For Battery Reactionsmentioning

confidence: 99%

Advances in Electrochemical Liquid-Phase Transmission Electron Microscopy for Visualizing Rechargeable Battery Reactions

Hu,

Yang,

Zeng

2024

ACS Nano

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“…The recently developed cryo-TEM technology could offer fresh and native structural information with minimal temperature-related artifacts, providing insights on the designing next generation rechargeable batteries. 176,187,188 Moreover, the current evaluation process in battery systems can be time-consuming, involving multiple anodes tested against the same cathode on an ad-hoc basis to link design parameters with cell performance. 189 To improve this inefficient process, artificial intelligence (AI)-based computational models can be utilized.…”

Section: Non-destructive Analysis Coordinated With Ai Technology For ...mentioning

confidence: 99%

“…Therefore, non‐destructive in‐situ and operando analysis are needed to better understand interface chemistry and accelerate exploration of advanced Li metals. The recently developed cryo‐TEM technology could offer fresh and native structural information with minimal temperature‐related artifacts, providing insights on the designing next generation rechargeable batteries 176,187,188 …”

Section: Challenges and Perspectivesmentioning

confidence: 99%

Toward thin and stable anodes for practical lithium metal batteries: A review, strategies, and perspectives

Lee,

Jeong,

Nam

et al. 2023

EcoMat

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The lithium metal battery (LMB) is a promising energy storage platform with a distinctively high energy density in theory, outperforming even those of conventional Li‐ion batteries. In practice, however, the actual achievable energy density of LMBs is significantly limited due to the Li metal anode (LMA) being too thick (50–250 μm), and there are difficulties with expanding the highly reactive Li metal into large‐format cells due to safety concerns. Therefore, the recent focus of LMB research is headed toward the development of a thin and stable LMA. However, as the thickness of Li anode decreases (≤20 μm) and the absolute size of the battery cell increases, interfacial reactions on the Li surface become more active, potentially leading to fatal thermal runaway. In this regard, there is still much demand for the development of novel manufacturing technologies to overcome this issue and produce thin and stable Li metal. Considering these things, in this review, we initially examine the fundamentals regarding the deployment of LMAs using a number of essential metrics. Then, we introduce recent strategies employed for designing thin and stable Li anodes including host matrix architecturing, interface stabilization, and other advanced modifications. Finally, we propose future directions for the realization of practical LMBs and their potential applications in various battery systems, encompassing Na, K, and Zn‐based batteries. We anticipate that ultra‐thin and ultra‐stable metal anodes would find widespread utilization in secondary battery applications with high‐power requirements.image

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“…The images formed are much less noisy from light emitted by a cold specimen. For similar reasons, transmission electron microscopy is used for samples cooled to cryogenic temperatures and is known as cryogenic electron microscopy (Cryo-EM) [19][20][21].…”

Section: Introductionmentioning

confidence: 99%

Mineral Characterization Using Scanning Electron Microscopy (SEM): A Review of the Fundamentals, Advancements, and Research Directions

Ali,

Zhang,

Santos

2023

Applied Sciences

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Scanning electron microscopy (SEM) is a powerful tool in the domains of materials science, mining, and geology owing to its enormous potential to provide unique insight into micro and nanoscale worlds. This comprehensive review discusses the background development of SEM, basic SEM operation, including specimen preparation and image processing, and the fundamental theoretical calculations underlying SEM operation. It provides a foundational understanding for engineers and scientists who have never had a chance to dig in depth into SEM, contributing to their understanding of the workings and development of this robust analytical technique. The present review covers how SEM serves as a crucial tool in mineral characterization, with specific discussion on the workings and research fronts of SEM-EDX, SEM-AM, SEM-MLA, and QEMSCAN. With automation gaining pace in the development of all spheres of technology, understanding the uncertainties in SEM measurements is very important. The constraints in mineral phase identification by EDS spectra and sample preparation are conferred. In the end, future research directions for SEM are analyzed with the possible incorporation of machine learning, deep learning, and artificial intelligence tools to automate the process of mineral identification, quantification, and efficient communication with researchers so that the robustness and objectivity of the analytical process can be improved and the analysis time and involved costs can be reduced. This review also discusses the idea of integrating robotics with SEM to make the equipment portable so that further mineral characterization insight can be gained not only on Earth but also on other terrestrial grounds.

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Expanding the cryogenic electron microscopy toolbox to reveal diverse classes of battery solid electrolyte interphase

Cited by 11 publications

References 59 publications

Advances in Electrochemical Liquid-Phase Transmission Electron Microscopy for Visualizing Rechargeable Battery Reactions

Advances in Electrochemical Liquid-Phase Transmission Electron Microscopy for Visualizing Rechargeable Battery Reactions

Toward thin and stable anodes for practical lithium metal batteries: A review, strategies, and perspectives

Mineral Characterization Using Scanning Electron Microscopy (SEM): A Review of the Fundamentals, Advancements, and Research Directions

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