Experimental and theoretical insights into the<i>trans</i>influence of organo-sulfur and -selenium ligands in 5,6-membered palladium(<scp>ii</scp>) cationic pincer complexes based on iminophosphoranes

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Experimental and theoretical insights into thetransinfluence of organo-sulfur and -selenium ligands in 5,6-membered palladium(ii) cationic pincer complexes based on iminophosphoranes

Abstract: Novel iminophosphorane based heterotridentate SNS and SNSe ligands with the general formula MeSC6H4P(Ph2)=NC6H4ER (ER= SMe 3a, SPh 3b, SeMe 3c, SePh 3d) and their corresponding Pd(II) cationic complexes with tetrafluoroborate...

Cited by 2 publications

References 60 publications

Improved syntheses of doubly naphthalene-bridged diphosphine and its diiminodiphosphorane derivatives linking two Cu(I) centers

Improved syntheses of doubly naphthalene-bridged diphosphine and its diiminodiphosphorane derivatives linking two Cu(I) centers

Pd(ii) NCSe–pincer complexes for regioselective cross-dehydrogenative coupling of arylthiophenes with hetero(arenes)

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