2023
DOI: 10.1039/d3dt00604b
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Experimental and theoretical magnetostructural studies on discrete heterometallic cyanide-bridged dinuclear FeIIIMnII and tetranuclear FeIII2CuII2 complexes bearing tripodal pyrazolyl borate and tetradentate phenolate-based ligands

Abstract: Two new complexes [FeIII(Tp)(CN)2(µ-CN)MnIICl(HL1)]•3DMF (1) and {[FeIII(Tp)(CN)(µ2-NC)2CuII(HL2)](ClO4)}2•6DMF (2) (HL1 = 2-((((1-methylbenzimidazol-2-yl)methyl)(pyridin-2-ylmethyl)amino)methyl)phenol and HL2 = 2-(((pyridin-2-ylmethyl)(quinolin-2-ylmethyl)-amino)methyl)phenol) have been synthesized and characterized by elemental analysis, IR, and UV/Vis spectroscopy. Structural analysis revealed...

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