Experimental and theoretical vibrational spectroscopic study on symmetric and asymmetric halo‐bridged complexes of palladium(II) and platinum(II)

Keßenich, Elmar; Schulz, Axel; Severin, Kay

doi:10.1002/jrs.698

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Combinatorial Catalysis With Bimetallic Complexes1

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“…Over the last years, we have developed very efficient and versatile methods, which allow the synthesis of bimetallic complex-es, in which two different metal fragments are connected by either two [2][3][4][5] or three [6][7][8] halogeno-bridges [9]. Some of the complexes, which are suited for the synthesis of asymmetric complexes with three halogeno-bridges are shown in Scheme 1.…”

Section: Combinatorial Catalysis With Bimetallic Complexesmentioning

confidence: 99%

New Catalysts and Receptors by Self-Assembly and Combinatorial Chemistry

Severin¹

2004

Chimia

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New methods that allow the generation of transition metal-based catalysts and receptors are discussed. It is shown that heterobimetallic, halogeno-bridged complexes are well-suited for screening assays in combinatorial catalysis. Metal catalysts with a structurally defined second coordination sphere can be obtained by molecular imprinting with pseudo-substrate conjugates as exemplified by the substrate-, regio- and stereoselective reduction of ketones, catalyzed by immobilized ruthenium and rhodium complexes. Macrocyclic complexes, formed by self-assembly of organometallic complexes, are shown to act as highly specific receptors for small cations and anions.

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