2005
DOI: 10.1016/j.gca.2005.03.002
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Experimental determination of the diffusion coefficient for calcium in olivine between 900°C and 1500°C

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Cited by 135 publications
(72 citation statements)
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“…An estimate of the minimum time it would take to homogenise the crystal with respect to Fe-Mg and Ca at magmatic temperatures can be obtained from the characteristic diffusion length (x0(Dt) 1/2 ; where x0distance, D0diffusivity, t0time) of each element of interest. Diffusion coefficients for Ca and Fe-Mg, parallel to the c-axis, were calculated using the models of Coogan et al (2005), and at a magmatic temperature of 1,170°C and an oxygen fugacity equivalent to the QFM buffer. For a typical 200-μm olivine crystal, Fe-Mg would have homogenised in approximately 0.2 years, and Ca in 10 years, providing a minimum estimate for the residence time of a crystal within this magma.…”
Section: Trace Element Systematicsmentioning
confidence: 99%
“…An estimate of the minimum time it would take to homogenise the crystal with respect to Fe-Mg and Ca at magmatic temperatures can be obtained from the characteristic diffusion length (x0(Dt) 1/2 ; where x0distance, D0diffusivity, t0time) of each element of interest. Diffusion coefficients for Ca and Fe-Mg, parallel to the c-axis, were calculated using the models of Coogan et al (2005), and at a magmatic temperature of 1,170°C and an oxygen fugacity equivalent to the QFM buffer. For a typical 200-μm olivine crystal, Fe-Mg would have homogenised in approximately 0.2 years, and Ca in 10 years, providing a minimum estimate for the residence time of a crystal within this magma.…”
Section: Trace Element Systematicsmentioning
confidence: 99%
“…Recent petrological studies of the Oman ophiolite and Hole 504B have developed techniques for estimating the cooling rates of dikes and gabbros (Coogan et al, 2005a(Coogan et al, , 2002(Coogan et al, , 2005bVanTongeren et al, 2008). The Ca in olivine geospeedometer developed and refined by Coogan and others will allow the robust estimation of vertical variations in cooling rate that are sensitive enough to identify departures from conductive cooling profiles.…”
Section: Is the Plutonic Crust Cooled By Conduction Or Hydrothermal Cmentioning
confidence: 99%
“…Other authors have found slightly different values for n: ∼ 1/5.8 (Buening and Buseck, 1973), ∼ 1/3.2, ∼ 1/5 and ∼ 1/4.5 for Mg, Fe and Mn respectively (Jurewicz and Watson, 1988) (note that for Fe diffusion along the a axis, these authors found n = −0.18), 1/4.25 (Petry et al, 2004) and found n between 1/5 and 1/7 (these authors also found that at low temperature and/or f O 2 < 10 −15 atm, n becomes much smaller). For Ca diffusion, for which we only have 2 data sets available, we chose n = 1/3.2 (Coogan et al, 2005) whereas Jurewicz and Watson (1988) found n ≃ 1/4.5.…”
Section: The Diffusion Datamentioning
confidence: 99%