Experimental study on the microreactor-assisted synthesis of phosphinic chlorides with varying steric hindrance

Abstract

An efficient and catalyst-free method for the preparation of optically active and racemic mono-substituted t-butyl phosphinic chlorides tBuRP(O)Cl under flow conditions was reported. A variety of mono t-butyl substituted phosphinic...

A tribute to Professor Jozef Drabowicz

“…He carried out parallel methodological research in the field of organic and asymmetric synthesis supplemented by works on the synthesis of compounds of "new materials" and the use of selected spectroscopic techniques (NMR, CD, VCD) in structural studies. Recently, Prof. Drabowicz began research on the use of flow techniques in the chemistry of hetero-organic compounds 16,17 and chiral polythiophene systems functionalized with substituents with stereogenic heteroatoms (Figure 7) as substrates in the synthesis of conductive organic materials. 18,19 POLYMER l em =552 nm Figure 7.…”