Chem. Sci.
 2024
DOI: 10.1039/d4sc05369a
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Exploring efficient and air-stable d2 Re(v) alkylidyne catalysts: toward room temperature alkyne metathesis

Mingxu Cui,
Jie Huang,
Long Yiu Tsang
et al.

Abstract: Transition metal-catalyzed alkyne metathesis has become a useful tool in synthetic chemistry. Well-defined alkyne metathesis catalysts comprise alkylidyne complexes of tungsten, molybdenum and rhenium. Non-d0 Re(V) alkylidyne catalysts exhibit advantages...

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