2022
DOI: 10.1016/j.jechem.2021.10.028
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Extended X-ray absorption fine structure (EXAFS) of FAPbI3 for understanding local structure-stability relation in perovskite solar cells

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Cited by 25 publications
(11 citation statements)
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“…Therefore, a close understanding of crystallization paths at the atomic level will benefit compositional and device engineering. Techniques such as EXAFS and pair distribution function (PDF) probes short-range atomic order and can help in this task itself, but combined with simulations, can go even close to atomic level transformation. , …”
Section: Discussionmentioning
confidence: 99%
“…Therefore, a close understanding of crystallization paths at the atomic level will benefit compositional and device engineering. Techniques such as EXAFS and pair distribution function (PDF) probes short-range atomic order and can help in this task itself, but combined with simulations, can go even close to atomic level transformation. , …”
Section: Discussionmentioning
confidence: 99%
“…All the data fitting processes were conducted through ATHENA. 41 EIS measurement data were obtained from an Autolab electrochemical working station with an amplitude of 20 mV at voltage ranging from 0.0 V to 1.0 V under one sun illumination. The frequency range was 1 MHz to 850 Hz.…”
Section: Methodsmentioning
confidence: 99%
“…Fluorine-doped tin oxide glass (FTO, T18VU70, 12−13 Ω/sq, AGC Fabritech Co., Ltd.) was cleaned by the method described in the literature. 55 For a thin SnO 2 electron transport layer, a diluted SnO 2 colloidal solution (15 wt %, Alfa Aesar) was spin coated according to the procedure reported elsewhere. 45 FAPbI 3 films were prepared according to the methods reported previosly, 45,55 where MACl and CsCl were included in the perovskite precursor solution (solvent was a dimethylformamide (DMF) and dimethyl sulfoxide (DMSO) mixture), diethyl ether was used for the antisolvent dropping process, and the annealing temperature and time were 150 °C and 10 min.…”
Section: Methodsmentioning
confidence: 99%
“…55 For a thin SnO 2 electron transport layer, a diluted SnO 2 colloidal solution (15 wt %, Alfa Aesar) was spin coated according to the procedure reported elsewhere. 45 FAPbI 3 films were prepared according to the methods reported previosly, 45,55 where MACl and CsCl were included in the perovskite precursor solution (solvent was a dimethylformamide (DMF) and dimethyl sulfoxide (DMSO) mixture), diethyl ether was used for the antisolvent dropping process, and the annealing temperature and time were 150 °C and 10 min. For the PVP−Idriven perovskite films, a stock solution was prepared by dissolving 10 mg of PVP−I (Merck, formula weight = 364.95 g/mol) in 1 mL of DMSO.…”
Section: Methodsmentioning
confidence: 99%
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