Fabric phase sorptive extraction/GC‐MS method for rapid determination of broad polarity spectrum multi‐class emerging pollutants in various aqueous samples

Kaur, Ramandeep; Kaur, Ripneel; Grover, Aman; Rani, Susheela; Malik, Ashok Kumar; Kabir, Abuzar; Furton, Kenneth G.

doi:10.1002/jssc.201900089

Cited by 17 publications

(8 citation statements)

References 31 publications

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“…Kaur et al in 2019 [51] developed and validated a rapid extraction and clean-up method using selective fabric phase sorptive extraction combined with gas chromatography and mass spectrometry for the determination of broad polarity spectrum emerging pollutants, ethyl paraben, butyl paraben, diethyl phthalate, dibutyl phthalate, lidocaine, prilocaine, triclosan, and bisphenol A in various aqueous samples. Some important parameters of fabric phase sorptive extraction such as extraction time, matrix pH, stirring speed, type, and volume of desorption solvent were investigated and optimized.…”

Section: Applicationsmentioning

confidence: 99%

Fabric Phase Sorptive Extraction: A Paradigm Shift Approach in Analytical and Bioanalytical Sample Preparation

Kabir

Samanidou

2021

Molecules

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Fabric phase sorptive extraction (FPSE) is an evolutionary sample preparation approach which was introduced in 2014, meeting all green analytical chemistry (GAC) requirements by implementing a natural or synthetic permeable and flexible fabric substrate to host a chemically coated sol–gel organic–inorganic hybrid sorbent in the form of an ultra-thin coating. This construction results in a versatile, fast, and sensitive micro-extraction device. The user-friendly FPSE membrane allows direct extraction of analytes with no sample modification, thus eliminating/minimizing the sample pre-treatment steps, which are not only time consuming, but are also considered the primary source of major analyte loss. Sol–gel sorbent-coated FPSE membranes possess high chemical, solvent, and thermal stability due to the strong covalent bonding between the fabric substrate and the sol–gel sorbent coating. Subsequent to the extraction on FPSE membrane, a wide range of organic solvents can be used in a small volume to exhaustively back-extract the analytes after FPSE process, leading to a high preconcentration factor. In most cases, no solvent evaporation and sample reconstitution are necessary. In addition to the extensive simplification of the sample preparation workflow, FPSE has also innovatively combined the extraction principle of two major, yet competing sample preparation techniques: solid phase extraction (SPE) with its characteristic exhaustive extraction, and solid phase microextraction (SPME) with its characteristic equilibrium driven extraction mechanism. Furthermore, FPSE has offered the most comprehensive cache of sorbent chemistry by successfully combining almost all of the sorbents traditionally used exclusively in either SPE or in SPME. FPSE is the first sample preparation technique to exploit the substrate surface chemistry that complements the overall selectivity and the extraction efficiency of the device. As such, FPSE indeed represents a paradigm shift approach in analytical/bioanalytical sample preparation. Furthermore, an FPSE membrane can be used as an SPME fiber or as an SPE disk for sample preparation, owing to its special geometric advantage. So far, FPSE has overwhelmingly attracted the interest of the separation scientist community, and many analytical scientists have been developing new methodologies by implementing this cutting-edge technique for the extraction and determination of many analytes at their trace and ultra-trace level concentrations in environmental samples as well as in food, pharmaceutical, and biological samples. FPSE offers a total sample preparation solution by providing neutral, cation exchanger, anion exchanger, mixed mode cation exchanger, mixed mode anion exchanger, zwitterionic, and mixed mode zwitterionic sorbents to deal with any analyte regardless of its polarity, ionic state, or the sample matrix where it resides. Herein we present the theoretical background, synthesis, mechanisms of extraction and desorption, the types of sorbents, and the main applications of FPSE so far according to different sample categories, and to briefly show the progress, advantages, and the main principles of the proposed technique.

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Section: Applicationsmentioning

confidence: 99%

Fabric Phase Sorptive Extraction: A Paradigm Shift Approach in Analytical and Bioanalytical Sample Preparation

Kabir

Samanidou

2021

Molecules

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“…Switchable hydrophobicity solvents were used as homogeneous liquid–liquid microextraction solvent for variety of CECs including N,N‐dimethylcyclohexylamine (DMCA), N,N‐diethylethanamine (TEA), and N,N‐benzyldimethylamine (DMBA), and absolute extraction recoveries were in the range of 51%–103% (Lasarte‐Aragones, Alvarez‐Lueje, Salazar, & Toledo‐Neira, 2019). Kaur et al (2019) developed a method using fabric phase sorptive extraction (FPSE) coupled with GC‐MS for the simultaneous determination of broad polarity spectrum CECs (including ethylparaben, butylparaben, diethyl phthalate, dibutyl phthalate, lidocaine, prilocaine, TCS, and BPA) in tap, ground, municipal, and wastewater samples. Based on the validation experiment and comparative results, they demonstrated that this measure was a rapid, reliable, and sensitive multi‐residue analytical method, since it took less time for sample preparation with satisfactory precision and recovery.…”

Section: Monitoringmentioning

confidence: 99%

Contaminants of emerging concern in aquatic environment: Occurrence, monitoring, fate, and risk assessment

Tang

Zhong

et al. 2020

Water Environment Research

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The present work provides a review focusing on contaminants of emerging concern (CECs) in aquatic environment, with an emphasis on their occurrence, monitoring, fate, and risk assessment in the research published in the scientific literature in 2019. Several studies revealed that these organic contaminants were detected in many water bodies and suspect, nontarget, and target screening provided an efficient detection for the co-existing organic substances with complex components. Wastewater resource recovery facilities were concurrently considered as a central source, and several specific chemicals have been found to be used as chemical markers to track the source of CECs in some urban watersheds. Reliable monitoring, reliable fate/toxicity assessment, and effective removal that consider CECs as a heterogeneous group rather than single substances will be the challenges for the research community in the future.

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“…In recent years, magnetic solid‐phase extraction (MSPE) technology shows a good application potential for the enrichment of trace analyte, due to its simple and fast operation, high processing efficiency, and wide range of applications [13,14]. MSPE adsorbents combine numerous advantages such as large surface area simple manipulation, high separation efficiency, high reusability, and environmental friendliness with magnetic microparticles placed in a solution or suspension containing analytes causing selective adsorption on solid surfaces [15–17]. Therefore, the synthesis of new adsorbents for MSPE is an urgent need.…”

Section: Introductionmentioning

confidence: 99%

Fe₃O₄ nanoparticles coated with polyhedral oligomeric silsesquioxanes and β‐cyclodextrin for magnetic solid‐phase extraction of carbaryl and carbofuran

Liu

Zhang

et al. 2020

J of Separation Science

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In this study, porous sandwich structure Fe 3 O 4 nanoparticles coated by polyhedral oligomeric silsesquioxanes and β-cyclodextrin were prepared by surface polymerization and were used as the magnetic solid phase extraction adsorbent for the extraction and determination of carbaryl and carbofuran. The Fe 3 O 4 nanoparticles coated with polyhedral oligomeric silsesquioxanes and β-cyclodextrin were characterized by Fourier transform infrared spectroscopy, X-ray diffraction, thermogravimetric analysis, vibrating sample magnetometry, and scanning electron microscopy. After optimizing the extraction conditions, a method that combined magnetic solid phase extraction with high-performance liquid chromatography was developed for the determination of carbaryl and carbofuran in apple. The method exhibited a good linearity in the range of 2-400 μg/kg for carbaryl and carbofuran (R 2 = 0.9995), respectively. The limits of detection were 0.5 μg/kg of carbaryl and 0.7 μg/kg for carbofuran in apple, respectively. Extraction recoveries ranged from 94.2 to 103.1% with the preconcentration factor of 300 and the relative standard deviations were less than 5.9%. These results indicated that the method combined magnetic solid phase extraction with high-performance liquid chromatography and was promising for the determination of carbaryl and carbofuran at trace amounts.

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Fabric phase sorptive extraction/GC‐MS method for rapid determination of broad polarity spectrum multi‐class emerging pollutants in various aqueous samples

Cited by 17 publications

References 31 publications

Fabric Phase Sorptive Extraction: A Paradigm Shift Approach in Analytical and Bioanalytical Sample Preparation

Fabric Phase Sorptive Extraction: A Paradigm Shift Approach in Analytical and Bioanalytical Sample Preparation

Contaminants of emerging concern in aquatic environment: Occurrence, monitoring, fate, and risk assessment

Fe₃O₄ nanoparticles coated with polyhedral oligomeric silsesquioxanes and β‐cyclodextrin for magnetic solid‐phase extraction of carbaryl and carbofuran

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Fabric phase sorptive extraction/GC‐MS method for rapid determination of broad polarity spectrum multi‐class emerging pollutants in various aqueous samples

Cited by 17 publications

References 31 publications

Fabric Phase Sorptive Extraction: A Paradigm Shift Approach in Analytical and Bioanalytical Sample Preparation

Fabric Phase Sorptive Extraction: A Paradigm Shift Approach in Analytical and Bioanalytical Sample Preparation

Contaminants of emerging concern in aquatic environment: Occurrence, monitoring, fate, and risk assessment

Fe3O4 nanoparticles coated with polyhedral oligomeric silsesquioxanes and β‐cyclodextrin for magnetic solid‐phase extraction of carbaryl and carbofuran

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Product

Resources

About

Fe₃O₄ nanoparticles coated with polyhedral oligomeric silsesquioxanes and β‐cyclodextrin for magnetic solid‐phase extraction of carbaryl and carbofuran