Facile access to mid-valent Group 5 and 6 metal synthons

Shaw, Thomas E.; Stern, Charlotte L.; Sattelberger, Alfred P.; Jurca, Titel

doi:10.1039/d3qi00910f

Inorg. Chem. Front.

2023

DOI: 10.1039/d3qi00910f

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Facile access to mid-valent Group 5 and 6 metal synthons

Thomas E. Shaw

Charlotte L. Stern

Alfred P. Sattelberger

et al.

Abstract: Group 5 and 6 metal chlorides, MClx (M = Ta, Nb, Mo, W) are easily and controllably reduced, in a stepwise fashion, by stoichiometric PhMe2SiH, yielding only PhMe2SiCl, a useful...

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Synthesis and structure of trans-HfCl4(OEt2)2 and cis-ReCl4(OEt2)2, and computational studies of Group 4 to Group 7 MCl4(OEt2)2 isomer preferences (M = Zr, Hf, Nb, Ta, Mo, W, Re)

Shaw,

Knapp,

Currie

et al. 2025

Polyhedron

View full text Add to dashboard Cite

Synthesis and structure of trans-HfCl4(OEt2)2 and cis-ReCl4(OEt2)2, and computational studies of Group 4 to Group 7 MCl4(OEt2)2 isomer preferences (M = Zr, Hf, Nb, Ta, Mo, W, Re)

Shaw,

Knapp,

Currie

et al. 2025

Polyhedron

View full text Add to dashboard Cite

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Facile access to mid-valent Group 5 and 6 metal synthons

Abstract: Group 5 and 6 metal chlorides, MClx (M = Ta, Nb, Mo, W) are easily and controllably reduced, in a stepwise fashion, by stoichiometric PhMe2SiH, yielding only PhMe2SiCl, a useful...

Cited by 1 publication

References 33 publications

Synthesis and structure of trans-HfCl4(OEt2)2 and cis-ReCl4(OEt2)2, and computational studies of Group 4 to Group 7 MCl4(OEt2)2 isomer preferences (M = Zr, Hf, Nb, Ta, Mo, W, Re)

Synthesis and structure of trans-HfCl4(OEt2)2 and cis-ReCl4(OEt2)2, and computational studies of Group 4 to Group 7 MCl4(OEt2)2 isomer preferences (M = Zr, Hf, Nb, Ta, Mo, W, Re)

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