Facile fabrication, structural and electrical investigations of cadmium sulfide nanoparticles for fuel cell performance

Abstract

In the present work, CdS nanoparticles were synthesized and analyzed for use in fuel cell applications. The X-ray diffraction investigation showed that CdS possesses a cubic polycrystalline structure. For the (111) plane, the average values of mean crystallite size, microstrain, and dislocation density were calculated and found to be 1.935 nm, 0.0758, and 0.267 nm−2. The average crystallite size was additionally calculated and found to be 2.02 nm using the modified Scherrer’s plot. The observed blue shift in the photoluminescence of CdS is caused by the quantum size impact of the nanocrystalline structure. A broad emission band at 590 nm is produced by the recombination of a hole in the valence band of CdS with an electron confined in a sulfur vacancy. The average Cd/S ratio is good and comparable, according to the EDS analysis, which is close to the theoretical values and almost exactly fits the ideal structure. A thermogravimetry diagram was used to establish the thermal stability of CdS across a wide range of temperatures. Fuel cell application features peaks were investigated by the cyclic voltammetry of CdS under various conditions. The linear sweep voltammetry was used to analyze the electrochemical performance of CdS electrodes in fuel cells. Electrochemical impedance spectroscopy (EIS) was also used and the results confirmed that nickel substrate is regarded as being superior to stainless steel in terms of performance.

Sodium Alginate–CdS Nanostructures: Reinforcing Chemoselectivity in Nitro-Organic Reduction and Dye Degradation through Photoinduced Electron Transfer

“…Although the structure lacks a distinct crystalline shape, it is possible to observe a few crystal planes under high-resolution conditions. These fringes have a spacing of 0.353 nm, which matches well with the d -spacing of the cubic CdS(111) crystallographic planes . However, the inset selected area electron diffraction (SAED) pattern shows very less distinctive diffraction rings suggesting the semicrystalline nature of CdS nanostructures due to the involvement of alginate.…”

“…These fringes have a spacing of 0.353 nm, which matches well with the d-spacing of the cubic CdS(111) crystallographic planes. 47 However, the inset selected area electron diffraction (SAED) pattern shows very less distinctive diffraction rings suggesting the semicrystalline nature of CdS nanostructures due to the involvement of alginate. The number of particles, which could be seen by the transmission electron microscope, is represented by the histogram (Figure 3i).…”