“…Despite the availability of numerous oxide hosts, such as borates, phosphates, tungstates, molybdates, and vanadates, the silicates were the preferential choice as they have good physicalthermal-chemical stability with a wide band gap and a low thermal expansion coefficient. [17][18][19] However, silicates are the most abundant option in nature and are categorized as ortho (1:4), meta (1:3) and pyro (2:7) depending upon the Si:O ratio. [20] Amongst various metasilicates, Na 4 Ca 4 Si 6 O 18 occurs as a ternary compound in the Na 2 O-CaO-SiO 2 system.…”