Facile Synthesis of MnO2 Nanoflowers/N-Doped Reduced Graphene Oxide Composite and Its Application for Simultaneous Determination of Dopamine and Uric Acid

Wan, Xuan; Yang, Shihui; Cai, Zhaotian; He, Quanguo; Ye, Yabing; Xia, Yueyuan; Li, Guangli; Liu, Jun

doi:10.3390/nano9060847

Cited by 99 publications

(52 citation statements)

References 57 publications

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“…The result shows that Ta 2 O 5 -ErGO/GCE dramatically improved electrochemical performances owing to the large specific surface area. For further investigation, the effective electroactive areas of various electrodes could be figured out by the Randles-Sevcik equation [21,22]:…”

Section: Electrochemical Characterization Of the Modified Electrodesmentioning

confidence: 99%

Electrochemical Sensing Fabricated with Ta2O5 Nanoparticle-Electrochemically Reduced Graphene Oxide Nanocomposite for the Detection of Oxytetracycline

Magesa

Dong

et al. 2020

Biomolecules

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A novel tantalum pentoxide nanoparticle-electrochemically reduced graphene oxide nanocomposite-modified glassy carbon electrode (Ta2O5-ErGO/GCE) was developed for the detection of oxytetracycline in milk. The composition, structure and morphology of GO, Ta2O5, and Ta2O5-ErGO were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Oxytetracycline electrochemical behavior on the bare GCE, GO/GCE, ErGO/GCE, and Ta2O5-ErGO/GCE was studied by cyclic voltammetry. The voltammetric conditions (including scan rate, pH, deposition potential, and deposition time) were systematically optimized. With the spacious electrochemical active area, the Ta2O5-ErGO/GCE showed a great magnification of the oxidation signal of oxytetracycline, while that of the other electrodes (GCE, GO/GCE, ErGO/GCE) could not reach the same level. Under the optimum conditions, the currents were proportional to the oxytetracycline concentration in the range from 0.2 to 10 μM, and a low detection limit of 0.095 μM (S/N = 3) was detectable. Moreover, the proposed Ta2O5-ErGO/GCE performed practically with satisfactory results. The preparation of Ta2O5-ErGO/GCE in the current work provides a minor outlook of detecting trace oxytetracycline in milk.

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Section: Electrochemical Characterization Of the Modified Electrodesmentioning

confidence: 99%

Electrochemical Sensing Fabricated with Ta2O5 Nanoparticle-Electrochemically Reduced Graphene Oxide Nanocomposite for the Detection of Oxytetracycline

Magesa

Dong

et al. 2020

Biomolecules

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“…TiO 2 NPs can be easily anchored on the surface of metal electrodes [43], but immobilizing them directly on the surface of glass carbon electrodes (GCE) is difficult. Due to their unique properties such as their large surface to-volume ratio, extraordinary electrical conductivity, and rapid electron transfer rate [44][45][46][47][48], graphene (Gr) has been considered as the most preferred electrode material for electrochemical sensors. Its unique 2D crystal structure and electronic property endows itself an ideal catalyst support for the anchoring of metal or metal oxide NPs [49], which offers versatile selective catalytic or sensing properties.…”

Section: Introductionmentioning

confidence: 99%

Titania/Electro-Reduced Graphene Oxide Nanohybrid as an Efficient Electrochemical Sensor for the Determination of Allura Red

Jin

et al. 2020

Nanomaterials

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Titania/electro-reduced graphene oxide nanohybrids (TiO2/ErGO) were synthesized by the hydrolysis of titanium sulfate in graphene oxide suspension and in situ electrochemical reduction. It provides a facile and efficient method to obtain nanohybrids with TiO2 nanoparticles (TiO2 NPs) uniformly coated by graphene nanoflakes. TiO2/ErGO nanohybrids were characterized by transmission electron microscopy, X-ray diffraction, cyclic voltammogram, and electrochemical impedance spectroscopy in detail. Compared with pure ErGO and TiO2 NPs, TiO2/ErGO nanohybrids greatly enhanced the electrocatalytic activity and voltammetric response of Allura Red. In the concentration range of 0.5–5.0 μM, the anodic peak currents of Allura Red were linearly correlated to their concentrations. However, the linear relationship was changed to the semi-logarithmic relationship at a higher concentration region (5.0–800 μM). The detection limit (LOD) was 0.05 μM at a signal-to-noise ratio of 3. The superior sensing performances of the proposed sensor can be ascribed to the synergistic effect between TiO2 NPs and ErGO, which provides a favorable microenvironment for the electrochemical oxidation of Allura Red. The proposed TiO2/ErGO/GCE showed good reproducibility and stability both in determination and in storage, and it can accurately detect the concentration of Allura Red in milk drinks, providing an efficient platform for the sensitive determination of Allura Red with high reliability, simplicity, and rapidness.

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“…Chemical modification of electrodes with suitable materials could solve these problems. Commonly, many nano structure materials such as polymer a nanocomposite [20][21][22][23][24][25], metal nanoparticles [26][27][28], and graphene nanocomposite [15,[29][30][31][32][33][34][35] have been introduced to enhance the electrode performance.…”

Section: Introductionmentioning

confidence: 99%

Application of carboxylic acid-functionalized of graphene oxide for electrochemical simultaneous determination of tryptophan and tyrosine in milk

Fooladi¹,

Razavizadeh²,

Noori³

et al. 2020

SN Appl. Sci.

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In this work, a new method for the simultaneous determination of tryptophan (Trp) and tyrosine (Tyr) in milk has been reported. Trp and Tyr are essential amino acids in human nutrition, but their electrochemical signal overlapped. For solve this problem, we developed modified Screen Printed Carbon Electrode (SPCE) with Graphene Oxide-COOH/Chitosan (GO-COOH/Chitosan) electro-deposition. The morphology and electrochemical performance of modified electrode were characterized by scanning electron microscopy, energy dispersive spectrometry, FT-IR, electrochemical impedance spectroscopy and cyclic voltammetry. The electrochemical simultaneous determination of Trp and Tyr has been investigated by using differential pulse voltammetry. The carboxylic acid functionalized GO modified SPCE was utilized to catalyze the oxidation of Trp and Tyr. Compared with SPCE/GO/Chitosan and SPCE/Chitosan sensor, the new sensor has enhanced sensitivity, low detection limit and high selectivity. In addition, the SPCE/GO-COOH-Chitosan sensor enhanced separation of the oxidation peak of Tyr and Trp and showed a remarkable increase in peak current for electroactive compounds, thus, it can be used for simultaneous voltammetric determination. Under the optimized experimental conditions, a linear correlation between oxidation peak current and concentration of Tyr and Trp in the ranges 0.1-60 µM and 0.4-40 µM with a detection limit of 0.05 µM (S/N = 3) and 0.1 µM (S/N = 3) were achieved, respectively. Finally, the proposed electrochemical sensor was applied for quantification of Tyr and Trp in milk samples, where standard solutions were spiked to the milk samples and recoveries were obtained.

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Facile Synthesis of MnO2 Nanoflowers/N-Doped Reduced Graphene Oxide Composite and Its Application for Simultaneous Determination of Dopamine and Uric Acid

Cited by 99 publications

References 57 publications

Electrochemical Sensing Fabricated with Ta2O5 Nanoparticle-Electrochemically Reduced Graphene Oxide Nanocomposite for the Detection of Oxytetracycline

Electrochemical Sensing Fabricated with Ta2O5 Nanoparticle-Electrochemically Reduced Graphene Oxide Nanocomposite for the Detection of Oxytetracycline

Titania/Electro-Reduced Graphene Oxide Nanohybrid as an Efficient Electrochemical Sensor for the Determination of Allura Red

Application of carboxylic acid-functionalized of graphene oxide for electrochemical simultaneous determination of tryptophan and tyrosine in milk

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