By chemical cross-linking the amidoxime group onto dual-surfaces of natural ore materials,n amely halloysite nanotubes (HNTs), an efficient adsorbent, AO-HNTs,i s developed. AO-HNTs show high uranium adsorption capacity of 456.24 mg g À1 in 32 ppm uranium-spiked simulated seawater.I nn atural seawater,A O-HNTs reach the high uranium extraction capacity of 9.01 mg g À1 after 30 days field test. The dual-surface amidoximated hollown anotubular AO-HNTs exhibit more coordination active sites for uranium adsorption, which is attributed to the high and fast uranium adsorption capacity.Because of the stable natural ore structure,AO-HNTs also show long service life.B enefiting from the low cost of HNTs,the cost for uranium extraction from seawater is close to the uranium price in the spot uranium market, suggesting that AO-HNTs could be used for economical extraction of uranium from the oceans.