Fast and effective simultaneous determination of metals in soil samples by ultrasound-assisted extraction and flame atomic absorption spectrometry: assessment of trace elements contamination in agricultural and native forest soils from Paraná - Brazil

Medeiros, Deborah Cristina Crominski da Silva; Piechontcoski, Fabiano; Watanabe, Erica Roberta Lovo da Rocha; Chaves, Enaura Helena Brandão; Inglez, Simone Delezuk

doi:10.1007/s10661-020-8065-0

Cited by 14 publications

(6 citation statements)

References 37 publications

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“…Following scientific literature reports [ 18 , 19 , 26 ], the ultrasound-assisted BCR sequential extraction method based on the use of ultrasound waves for heavy metal extraction allows similar results in comparison with the conventional BCR extraction method to be obtained. However, the extraction efficiency of heavy metals from solid samples like sewage sludge depends on several factors and technical parameters of the process, i.e., the type of ultrasound processor, the frequency and intensity characteristics of the wave, the sonication time, and the temperature [ 25 , 26 , 31 ]. Therefore, the optimization of different factors that have an impact on the process of ultrasound-assisted BCR sequential extraction is important in order to obtain results which are comparable to those achieved by the conventional method.…”

Section: Resultsmentioning

confidence: 99%

“…However, taking into account the number of scientific papers referencing the use of ultrasound waves in the process of the sequential extraction of heavy metals from soils or sediments [ 19 , 23 , 31 , 32 , 33 , 34 , 35 , 36 ], there are still only a few studies that concern sewage sludge [ 5 , 18 , 24 , 25 , 26 ]. Therefore, we decided to undertake research in this direction.…”

Section: Resultsmentioning

confidence: 99%

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A Comparison of Conventional and Ultrasound-Assisted BCR Sequential Extraction Methods for the Fractionation of Heavy Metals in Sewage Sludge of Different Characteristics

2022

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The purpose of this study was to determine the heavy metal (HM: Cd, Cr, Cu, Ni, Pb, Zn, and Hg) content in particular chemical fractions (forms) of sewage sludge with different characteristics (primary and dewatered sludge) using conventional (CSE) and ultrasound-assisted (USE) BCR sequential extraction methods (Community Bureau of Reference, now the Standards, Measurements and Testing Programme). The concentrations of HMs were determined using inductively coupled plasma optical spectrometry (ICP-OES). Only mercury was assayed with cold vapor atomic absorption spectrometry (CVAAS). Ultrasound treatment was conducted in the ultrasonic bath (Sonic 5, Polsonic). The optimal sonication time (30 min) was determined using ERM-CC144 (Joint Research Center; JCR) certified reference material. The conducted experiment revealed that the use of ultrasound waves shortened the extraction time to 4 h and 30 min (Stages I to III). The recoveries (RM) of heavy metals ranged from 62.8% to 130.2% (CSE) and from 79.8% to 135.7% (USE) for primary sludge, and from 87.2% to 113.2% (CSE) and from 87.8% to 112.0% (USE) for dewatered sludge. The only exception was Hg in dewatered sludge. The conducted research revealed minor differences in the concentrations and fractionation patterns for Cd, Ni, and Zn extracted from sludge samples by the tested methods. However, it was confirmed that the above findings do not significantly affect the results of a potential ecological risk assessment (with minor exceptions for Cd and Zn in the primary sludge), which is extremely essential for the natural use of sludge, and especially dewatered sludge (the final sludge). The shorter extraction time and lower energy consumption prove that ultrasound-assisted extraction is a fast and simple method for HM fractionation, and that it provides an alternative to the conventional procedure. Therefore, it can be considered a “green method” for the assessment of the bioavailability and mobility of heavy metals in solid samples.

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Section: Resultsmentioning

confidence: 99%

Section: Resultsmentioning

confidence: 99%

A Comparison of Conventional and Ultrasound-Assisted BCR Sequential Extraction Methods for the Fractionation of Heavy Metals in Sewage Sludge of Different Characteristics

2022

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“…The concentrations of macroelements (Ca, Na, K, and Mg), trace elements (Cu, Zn, Mn, Fe, and Cd), and microelements in the samples was performed via FAAS [ 35 , 36 , 37 ], using a ContrAA ® 700 spectrometer whose main characteristics are presented in Table 1 .…”

Section: Methodsmentioning

confidence: 99%

Impact of Soil Pollution on Melliferous Plants

Bărbulescu

Barbeș

Dumitriu

2022

Toxics

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This study aims at providing bee products and derivatives of medicinal plant consumers with a multifaceted perspective on mineral elements occurring in the soils of two forest zones in the vicinity of North Dobrogea (Romania) by (1) analyzing the pollution levels of the soils at three sites (denoted by DS, PH, and ST) in the study region, using different indicators; (2) providing the results of the transfer of metals from the soil to Sambucus nigra L. (SnL), Hypericum perforatum (Hp), and Tilia tomentosa (Tt). The statistical analysis of the series collected at these locations shows no difference between the elements’ concentrations (as a whole). Still, the values of the geo-accumulation index (Igeo) classify the soils as being soils that are moderately to highly contaminated with Cd (and not contaminated with Cu, Mn, or Zn) with respect to the European background values. The cumulative indices—the degree of contamination (DC), the pollution load index (PLI), the Nemerow integrated pollution index (NIPI), and the potential ecological risk index (PERI) indicated the highest contamination in DS (which is a tourist area). To assess the accumulation of different metals in plants, the enrichment factors (EF) were computed. In over 75% of cases, EF was above 1, indicating a high degree of enrichment with different metals. The highest values were those for Cu (41.10 in DS for SnL), and Cd (12.85 in DS for Tt). The results showed that there were different degrees of accumulation between microelements and trace elements in the plants. Tt acted as a bioaccumulator for almost all of the studied elements (K, Mg, Na, Fe, Mn, Cu, Zn, and Cd).

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“…The most common analytical techniques for the quantification and identification of chemical pollutants are flame atomic absorption spectrometry (FAAS) [ 24 , 25 ], atomic absorption spectrometry (AAS) [ 26 , 27 ], gas/liquid chromatography–mass spectrometry [ 28 , 29 ], inductively coupled plasma mass spectroscopy (ICP–MS) [ 30 , 31 ], inductively coupled plasma atomic emission spectroscopy (ICP–AES) [ 32 , 33 ], high performance liquid chromatography (HPLC)–fluorescence (FL) [ 34 , 35 ] and ultraviolet (UV) detection [ 36 , 37 ], and quantitative polymerase chain reaction (qPCR) [ 38 , 39 ]. Although the above-mentioned analytical protocols have shown very high sensitivity and specificity, these techniques are limited by either a long procedure of sample preparation or complicated equipment.…”

Section: Introductionmentioning

confidence: 99%

Gold–Carbon Nanocomposites for Environmental Contaminant Sensing

et al. 2021

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The environmental crisis, due to the rapid growth of the world population and globalisation, is a serious concern of this century. Nanoscience and nanotechnology play an important role in addressing a wide range of environmental issues with innovative and successful solutions. Identification and control of emerging chemical contaminants have received substantial interest in recent years. As a result, there is a need for reliable and rapid analytical tools capable of performing sample analysis with high sensitivity, broad selectivity, desired stability, and minimal sample handling for the detection, degradation, and removal of hazardous contaminants. In this review, various gold–carbon nanocomposites-based sensors/biosensors that have been developed thus far are explored. The electrochemical platforms, synthesis, diverse applications, and effective monitoring of environmental pollutants are investigated comparatively.

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Fast and effective simultaneous determination of metals in soil samples by ultrasound-assisted extraction and flame atomic absorption spectrometry: assessment of trace elements contamination in agricultural and native forest soils from Paraná - Brazil

Cited by 14 publications

References 37 publications

A Comparison of Conventional and Ultrasound-Assisted BCR Sequential Extraction Methods for the Fractionation of Heavy Metals in Sewage Sludge of Different Characteristics

A Comparison of Conventional and Ultrasound-Assisted BCR Sequential Extraction Methods for the Fractionation of Heavy Metals in Sewage Sludge of Different Characteristics

Impact of Soil Pollution on Melliferous Plants

Gold–Carbon Nanocomposites for Environmental Contaminant Sensing

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