Fast Determination of Toxic Arsenic Species in Food Samples Using Narrow-bore High-Performance Liquid-Chromatography Inductively Coupled Plasma Mass Spectrometry

Terol, Amanda; Marcinkowska, Monika; Ardini, Francisco; Grotti, Marco

doi:10.2116/analsci.32.911

Cited by 14 publications

(4 citation statements)

References 37 publications

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“…In this sense, methanol is more widely used than acetonitrile for RPC mobile phases [109,111]. Meanwhile, desolvation the liquid aerosol before it reaches the ICP, simple flow splitting after the HPLC column, or the use of a small bore or microbore column is also adopted to reduce the amount of organic solvent introduced into the detector [98,173,174].…”

Section: Detection Techniques For Speciation Analysismentioning

confidence: 99%

Speciation Analysis of Trace Arsenic, Mercury, Selenium and Antimony in Environmental and Biological Samples Based on Hyphenated Techniques

Liu

Guo

et al. 2019

Molecules

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In order to obtain a well understanding of the toxicity and ecological effects of trace elements in the environment, it is necessary to determine not only the total amount, but also their existing species. Speciation analysis has become increasingly important in making risk assessments of toxic elements since the toxicity and bioavailability strongly depend on their chemical forms. Effective separation of different species in combination with highly sensitive detectors to quantify these particular species is indispensable to meet this requirement. In this paper, we present the recent progresses on the speciation analysis of trace arsenic, mercury, selenium and antimony in environmental and biological samples with an emphasis on the separation and detection techniques, especially the recent applications of high performance liquid chromatography (HPLC) hyphenated to atomic spectrometry or mass spectrometry.

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Section: Detection Techniques For Speciation Analysismentioning

confidence: 99%

Speciation Analysis of Trace Arsenic, Mercury, Selenium and Antimony in Environmental and Biological Samples Based on Hyphenated Techniques

Liu

Guo

et al. 2019

Molecules

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“…The amount of arsenic is usually detected by hydride generation atomic fluorescence spectrometry [ 7 ], hydride generation atomic absorption spectrometry [ 8 ], hydride generation inductively-coupled plasma mass spectrometry [ 9 ], high-performance liquid chromatography with chemical vapor generation [ 10 ], and electrospray MS [ 11 ]. On the other hand, chemical analysis systems are costly to use and sustain, and require fully equipped laboratories and complicated sampling processes.…”

Section: Introductionmentioning

confidence: 99%

Gold nanoparticles/over-oxidized poly-eriochrome black T film modified electrode for determination of arsenic

AFŞAR¹,

ELÇİ²,

DURSUN³

2022

Turkish Journal of Chemistry

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A glassy carbon electrode, modified with gold nanoparticles/over-oxidized poly-eriochrome black T film, was fabricated for sensitive determination of As(III) by stripping voltammetry in an acidic medium. The electrode surface properties were characterized by cyclic voltammetry, electrochemical impedance spectroscopy, scanning electron microscope (SEM), and X-ray photoelectron spectroscopy (XPS). The electrode demonstrated a good response towards As(III), with a detection of 0.077 μ M and good linearity in the range of 0.1 to 10 μM (R 2 = 0.9977). For the determination of As(III), the fabricated electrode was placed in different mineral water samples, acidified with 0.75 M HCl solution, spiked with various concentrations of As(III). Spiked recoveries for mineral water samples were obtained in the range of 100.3%–105.0%. The relative standard deviations were lower than 4.0%.

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“…The existing HPLC-ICP-MS methods commonly used for As speciation are not optimized for the selective and fast analysis of only inorganic As(III) and As(V). − Only a few applications on the selective and rapid speciation of inorganic arsenic species can be found in the literature. , The best result in terms of analysis time was obtained by Marcinkowska et al, who proposed an HPLC-ICP-MS method to analyze inorganic As(III) and As(V) within 3 min.…”

mentioning

confidence: 99%

Introducing Frontal Chromatography–Inductively Coupled Plasma-Mass Spectrometry as a Fast Method for Speciation Analysis: The Case of Inorganic Arsenic

et al. 2019

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A frontal chromatography–ICP-MS method (FC-ICP-MS) is proposed as an innovative approach for fast elemental speciation analysis: inorganic arsenic speciation was selected as the first case study to prove the feasibility of the technique and to explore its potentialities and limits. The principal benefits of the FC-ICP-MS approach are the short analysis time and the very simple instrumental setup. As(III) and As(V) front separation is performed over a strong anion exchanger at pH 7.5. After the optimization of the instrumental setup and the frontal chromatographic parameters, As(III) and As(V) concentrations up to 240 μg/kg can be determined within 120–140 s using different univariate and multivariate calibration approaches. Best results in terms of accuracy in prediction were obtained using the partial least squares (PLS) calibration achieving limits of detection of 0.18 and 0.21 μg/kg for As(III) and As(V), respectively. This approach was also used to establish the figures of merit of the method. The proved feasibility and good performances (in terms of analysis time and accuracy) of this technique lay the groundwork for future applications of FC-ICP-MS for the speciation of other elements.

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Fast Determination of Toxic Arsenic Species in Food Samples Using Narrow-bore High-Performance Liquid-Chromatography Inductively Coupled Plasma Mass Spectrometry

Cited by 14 publications

References 37 publications

Speciation Analysis of Trace Arsenic, Mercury, Selenium and Antimony in Environmental and Biological Samples Based on Hyphenated Techniques

Speciation Analysis of Trace Arsenic, Mercury, Selenium and Antimony in Environmental and Biological Samples Based on Hyphenated Techniques

Gold nanoparticles/over-oxidized poly-eriochrome black T film modified electrode for determination of arsenic

Introducing Frontal Chromatography–Inductively Coupled Plasma-Mass Spectrometry as a Fast Method for Speciation Analysis: The Case of Inorganic Arsenic

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