Fe(III), Cu(II) and U(VI) binuclear complexes with a new isothiosemicarbazone ligand: Syntheses, characterization, crystal structures, thermal behavior and theoretical investigations

Mahjoobizadeh, Milad; Takjoo, Reza; Farhadipour, Abolghasem; Mague, Joel T.

doi:10.1016/j.ica.2018.07.011

Cited by 3 publications

(2 citation statements)

References 44 publications

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“…Transmission factors: Tmin/Tmaxwas about 0.786/0.987. The structure was solved by direct methods by using SHELXL-2015 and SHELXL-2017 programs (Sheldrick, 2015 and Sheldrick, 2017) [16] and refined on F2 by the full-matrix least-squares methods, the nonhydrogen atoms were subjected to anisotropic refinement and the hydrogen atoms were included in geometric positions but not refined.…”

Section: X-ray Diffractionmentioning

confidence: 99%

Synthesis, characterizations, crystal structure, inhibition effects and theoretical study of novel Schiff base on the corrosion of carbon steel in 1 M HCl

Boukazoula

Haffar²,

Bourzami³

et al. 2022

Journal of Molecular Structure

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Section: X-ray Diffractionmentioning

confidence: 99%

Synthesis, characterizations, crystal structure, inhibition effects and theoretical study of novel Schiff base on the corrosion of carbon steel in 1 M HCl

Boukazoula

Haffar²,

Bourzami³

et al. 2022

Journal of Molecular Structure

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“…CMe) 2 •2H 2 O in hot EtOH; the yield was ≈85%. The two uranyl(VI) dications are bridged by a 2.11 acetate group and each (L 26 ) 2− ion behaves as a tetradentate chelating O 2 N 2 ligand (1.111100)[103].…”

mentioning

confidence: 99%

Oligonuclear Actinoid Complexes with Schiff Bases as Ligands—Older Achievements and Recent Progress

Tsantis

Tzimopoulos

Hołyńska

et al. 2020

IJMS

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Even 155 years after their first synthesis, Schiff bases continue to surprise inorganic chemists. Schiff-base ligands have played a major role in the development of modern coordination chemistry because of their relevance to a number of interdisciplinary research fields. The chemistry, properties and applications of transition metal and lanthanoid complexes with Schiff-base ligands are now quite mature. On the contrary, the coordination chemistry of Schiff bases with actinoid (5f-metal) ions is an emerging area, and impressive research discoveries have appeared in the last 10 years or so. The chemistry of actinoid ions continues to attract the intense interest of many inorganic groups around the world. Important scientific challenges are the understanding the basic chemistry associated with handling and recycling of nuclear materials; investigating the redox properties of these elements and the formation of complexes with unusual metal oxidation states; discovering materials for the recovery of trans-{UVIO2}2+ from the oceans; elucidating and manipulating actinoid-element multiple bonds; discovering methods to carry out multi-electron reactions; and improving the 5f-metal ions’ potential for activation of small molecules. The study of 5f-metal complexes with Schiff-base ligands is a currently “hot” topic for a variety of reasons, including issues of synthetic inorganic chemistry, metalosupramolecular chemistry, homogeneous catalysis, separation strategies for nuclear fuel processing and nuclear waste management, bioinorganic and environmental chemistry, materials chemistry and theoretical chemistry. This almost-comprehensive review, covers aspects of synthetic chemistry, reactivity and the properties of dinuclear and oligonuclear actinoid complexes based on Schiff-base ligands. Our work focuses on the significant advances that have occurred since 2000, with special attention on recent developments. The review is divided into eight sections (chapters). After an introductory section describing the organization of the scientific information, Sections 2 and 3 deal with general information about Schiff bases and their coordination chemistry, and the chemistry of actinoids, respectively. Section 4 highlights the relevance of Schiff bases to actinoid chemistry. Sections 5–7 are the “main menu” of the scientific meal of this review. The discussion is arranged according the actinoid (only for Np, Th and U are Schiff-base complexes known). Sections 5 and 7 are further arranged into parts according to the oxidation states of Np and U, respectively, because the coordination chemistry of these metals is very much dependent on their oxidation state. In Section 8, some concluding comments are presented and a brief prognosis for the future is attempted.

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Structural and theoretical studies of iron(III) and copper(II) complexes of dianion N1,N4-bis(salicylidene)-S-alkyl-thiosemicarbazide

Takjoo

Ramasami

Rhyman

et al. 2022

Journal of Molecular Structure

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Fe(III), Cu(II) and U(VI) binuclear complexes with a new isothiosemicarbazone ligand: Syntheses, characterization, crystal structures, thermal behavior and theoretical investigations

Cited by 3 publications

References 44 publications

Synthesis, characterizations, crystal structure, inhibition effects and theoretical study of novel Schiff base on the corrosion of carbon steel in 1 M HCl

Synthesis, characterizations, crystal structure, inhibition effects and theoretical study of novel Schiff base on the corrosion of carbon steel in 1 M HCl

Oligonuclear Actinoid Complexes with Schiff Bases as Ligands—Older Achievements and Recent Progress

Structural and theoretical studies of iron(III) and copper(II) complexes of dianion N1,N4-bis(salicylidene)-S-alkyl-thiosemicarbazide

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