Ferrocene-contained metal organic frameworks: From synthesis to applications

Huang, Zhongwei; Yu, Haojie; Liu, Xiaowei; Lin, Tengfei; Haq, Fazal; Vatsadze, Sergey Z.; Lemenovskiy, Dmitry A.

doi:10.1016/j.ccr.2020.213737

Cited by 96 publications

(59 citation statements)

References 87 publications

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“…In the first step, the Friedel-Crafts acylation reaction of the ferrocene was implemented to obtain 4-chlorobutyroylferrocene (2). Subsequently, 4chlorobutylferrocene (3) was synthesized with in situ reductions of compound 2 with the solution of NaBH 4 in diglyme.…”

Section: Synthesis Of Ferrocene-based Estersmentioning

confidence: 99%

“…The application of ferrocene-based organometallic compounds has been widely studied in recent years. [1][2][3] It has been ascertained that ferrocene-based organic materials could be hired in a wide range of electrochemical applications like supercapacitors, [4][5][6] solar cells, and fuel cells. [2,[7][8][9][10][11] Moreover, their indirect applications in drug delivery and medical approaches have been demonstrated.…”

Section: Introductionmentioning

confidence: 99%

“…[1][2][3] It has been ascertained that ferrocene-based organic materials could be hired in a wide range of electrochemical applications like supercapacitors, [4][5][6] solar cells, and fuel cells. [2,[7][8][9][10][11] Moreover, their indirect applications in drug delivery and medical approaches have been demonstrated. [12][13][14] The catalytic activity of ferrocene-based materials is broadly discussed in state-of-the-art.…”

Section: Introductionmentioning

confidence: 99%

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Synthesis of ferrocene‐based esters by alkylation of carboxylate ions and investigation of their electrochemical and optical behaviors

Jamali

Teimuri‐Mofrad

2021

Applied Organom Chemis

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The synthesis of new ferrocene‐based esters has been studied with the alkylation of a variety of carboxylic acids with potassium carbonate as a base. The effect of various ferrocenyl‐based alkyl halides has been examined and proclaimed that 4‐iodobutylferrocene is the most useful initial reagent for synthesizing novel ferrocene‐based esters. Dimethyl sulfoxide (DMSO) has been used as the solvent at room temperature without catalysts with acceptable reaction yields in the optimized procedure. Cyclic voltammetry (CV) has been performed as the first method to exhibit the potential application of the synthesized esters in electrochemical approaches. The CV results confirm the satisfying reversible electrochemical behavior of 4‐ferrocenylbutyl phenylacetate (7h). Additionally, the optical behavior of the synthesized solvatochromic esters has been investigated in acetonitrile utilizing spectrophotometric measurements. The optical studies manifest potential for optical uses, such as photosensor applications.

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Section: Synthesis Of Ferrocene-based Estersmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Synthesis of ferrocene‐based esters by alkylation of carboxylate ions and investigation of their electrochemical and optical behaviors

Jamali

Teimuri‐Mofrad

2021

Applied Organom Chemis

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“…Metal–organic frameworks (MOFs), consisting of the metal ions/cluster centers and organic ligands through coordination interactions, exhibit unique merits including high porosity, large specific surface area and tunable structure [ 24 – 26 ], enabling them huge promising application in various areas such as heterogeneous catalysts[ 27 ], energy storage and conversion [ 28 , 29 ], gas separation [ 30 , 31 ], sensing [ 32 , 33 ] and biomedicine [ 34 ]. In 2015, the first MOF-derived MAM sample was reported by Liu and co -workers [ 35 ].…”

Section: Introductionmentioning

confidence: 99%

State of the Art and Prospects in Metal-Organic Framework-Derived Microwave Absorption Materials

et al. 2022

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Microwave has been widely used in many fields, including communication, medical treatment and military industry; however, the corresponding generated radiations have been novel hazardous sources of pollution threating human’s daily life. Therefore, designing high-performance microwave absorption materials (MAMs) has become an indispensable requirement. Recently, metal–organic frameworks (MOFs) have been considered as one of the most ideal precursor candidates of MAMs because of their tunable structure, high porosity and large specific surface area. Usually, MOF-derived MAMs exhibit excellent electrical conductivity, good magnetism and sufficient defects and interfaces, providing obvious merits in both impedance matching and microwave loss. In this review, the recent research progresses on MOF-derived MAMs were profoundly reviewed, including the categories of MOFs and MOF composites precursors, design principles, preparation methods and the relationship between mechanisms of microwave absorption and microstructures of MAMs. Finally, the current challenges and prospects for future opportunities of MOF-derived MAMs are also discussed."Image missing"

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“…[ 1‐4 ] Compared with zeolites, active carbons, and mesoporous silicas, MOFs possess particular features, such as tunable structures, facile functionalization and incorporation of active sites. [ 5‐9 ] Thanks to these unique advantages, the application fields of MOFs cover gas storage/separation, [ 10‐13 ] catalysis, [ 14‐17 ] sensing, [ 18‐22 ] environmental remediation, [ 23‐27 ] proton conduction, [ 28‐31 ] energy storage, [ 32‐34 ] and even biomedical applications. [ 35‐38 ] Nevertheless, the large‐ scale commercialization of MOFs is seriously limited because of their intrinsic fragility, mechanical instability, and unworkability.…”

Section: Introductionmentioning

confidence: 99%

Recent Progress in Metal‐Organic Frameworks@Cellulose Hybrids and Their Applications

et al. 2021

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In recent years, metal‐organic frameworks (MOFs) are attracting increasing attention due to their charming properties. However, the intrinsic fragility, powdered crystalline state, and poor processibility of MOFs hinder their further application. By this, the designs of MOF‐based aerogels, hydrogels, membranes are effective ways to solve this problem. Graphene, silica, synthetic polymer and cellulose are the commonly used raw materials for fabricating MOF‐based aerogels, hydrogels, and membranes. Among them, cellulose and its derivatives are the best candidates to support the powdered MOFs from the perspectives of economy, environmental protection and property. This review focuses on discussing the advantages of MOF@cellulose hybrids in applications such as water treatment, antibacterial, gas separation and adsorption, energy storage, drug delivery, catalysis, and other smart composites. MOF@cellulose‐based aerogels, hydrogels and membranes can provide valuable guidance for investigating the practical application of MOFs in terms of processability, reusability, stability and easiness in handling.

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Ferrocene-contained metal organic frameworks: From synthesis to applications

Cited by 96 publications

References 87 publications

Synthesis of ferrocene‐based esters by alkylation of carboxylate ions and investigation of their electrochemical and optical behaviors

Synthesis of ferrocene‐based esters by alkylation of carboxylate ions and investigation of their electrochemical and optical behaviors

State of the Art and Prospects in Metal-Organic Framework-Derived Microwave Absorption Materials

Recent Progress in Metal‐Organic Frameworks@Cellulose Hybrids and Their Applications

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