First cyano-bridged coordination polymers based on N,N’-chelated Ag(I) ions and octahedral rhenium(III) chalcocyanide clusters exhibiting unusually long-lived photoluminescence

Ermolaev, A. V.; Смоленцев, А. И.; Brylev, Konstantin A.; Kitamura, Noboru; Mironov, Yuri V.

doi:10.1016/j.molstruc.2018.07.028

Cited by 14 publications

(3 citation statements)

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“…Hofmann-3-phenylpropylamine (3PPA) type Hofmann-type CPs compounds with chemical formula of M(3PPA) 2 Ni(CN) 4 , where M can be Ni (137), Co (138), Cd (139), and Pd (140) have been synthetized and their Raman vibrational spectra were reported in the region of 4000-60 cm −1 . [136] The vibrational bands originating from the 3PPA ligand molecules, the polymeric sheet, and the metal-ligand interactions within the compounds are assigned.…”

Section: Structure Analysis Of Hofmann-type Cn-cpsmentioning

confidence: 99%

“…[1] The opportunity to construct CN-CPs materials in the 3D, 2D, and 1D was made possible by the DOI: 10.1002/smll.202306709 cyanide groups' capacity to serve as a bridge between the metal ions, [2] and clusters in addition to polynuclear complexes. [3,4] Notably, the cyanide anions are the most basic species that combine carbon and nitrogen. They involve accepting (back-bonding) from the lowest unoccupied molecular orbital (LUMO) and donating from the highest occupied molecular orbital (HOMO).…”

Section: Introductionmentioning

confidence: 99%

“…Additionally, even a minor external input, such a change in temperature or humidity, can shift the flexible layered structures. High humidity causes the material to have water molecules that are both coordinated and uncoordinated (interstitial), such as Mn(H 2 O) 2 [Ni (CN) 4 ].3H 2 O. [45] These water molecules are crucial in the alteration of the crystal structure during topotactic dehydration, which preserves the crystal structure.…”

Section: Introductionmentioning

confidence: 99%

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Hofmann‐Type Cyanide Bridged Coordination Polymers for Advanced Functional Nanomaterials

Hegazy,

Hassan,

2023

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Since the discovery of Hofmann clathrates of inorganic cyanide bridged coordination polymers (Hofmann‐type CN‐CPs), extensive research is done to understand their behavior during spin transitions caused by guest molecules or external stimuli. Lately, research on their nanoscale architectures for sensors and switching devices is of interest. Their potential is reported for producing advanced functional inorganic materials in two‐dimensional (2D) morphology using a scalable solid‐state thermal treatment method. For instance, but not restricted to, alloys, carbides, chalcogenides, oxides, etc. Simultaneously, their in situ crystallization at graphene oxide (GO) nanosheet surfaces, followed by a subsequent self‐assembly to build layered lamellar structures, is reported providing hybrid materials with a variety of uses. Hence, an overview of the most recent developments is presented here in the synthesis of nanoscale structures, including thin films and powders, using Hofmann‐type CN‐CPs. Also thoroughly demonstrated are the most recent synthetic ideas with the modest control over the size and shape of nanoscale particles. Additionally, in order to create new functional hybrid materials for electrical and energy applications, their thermal decomposition in various environments and hybridization with GO and other guest molecules is examined. This review article also conveyed their spin transition, astounding innovative versatile adhesives, and structure features.

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Section: Structure Analysis Of Hofmann-type Cn-cpsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%