First example of latices synthesis via oligomerization of norbornene in aqueous emulsions, catalyzed by palladium chloride

Eychenne, P.; Pérez, Emile; Rico, I.; Bon, Maryse; Lattes, Armand; Moisand, A.

doi:10.1007/bf00659294

Cited by 31 publications

(22 citation statements)

References 18 publications

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“…[62] A study on the polymerization of norbornene in a water dispersion or in an aqueous emulsion has been reported. [63] The polymerization was carried out in a water dispersion by heating water, norbornene and PdCl 2 (molar ratio norbornene : catalyst = 100) at 70 8C over 24 h. After a 15-20-min induction period, the polymer precipitated as a powder. The poly(norbornene) was insoluble in conventional solvents.…”

Section: Palladium Catalystsmentioning

confidence: 99%

The Vinyl Homopolymerization of Norbornene

Janiak¹,

Lassahn

2001

Macromol. Rapid Commun.

210

145

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Section: Palladium Catalystsmentioning

confidence: 99%

The Vinyl Homopolymerization of Norbornene

Janiak¹,

Lassahn

2001

Macromol. Rapid Commun.

210

145

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“…However, there are only two reports of these polymerizations in aqueous media, namely, the oligomerization of norbornene (Eychenne et al, 1993) and the alternating copolymerization of ethylene and carbon monoxide (Jiang and Sen, 1994). In the case of the oligomerization of norbornene, a 'micro-latex' was obtained with an average particle diameter of approximately 10 nm with PdCl 2 as the catalyst and sodium dodecylsulfate as the surfactant.…”

Section: Transition Metal Catalyzed Emulsion Polymerizationmentioning

confidence: 99%

Emulsion Polymerization

Aerdts¹,

Herk²,

Klumperman³

et al. 2013

Materials Science and Technology

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The sections in this article are Polymerization Techniques Emulsion Polymerization Mini‐ and Micro‐Emulsion Polymerization Basic Principles of Emulsion Polymerization Particle Nucleation Particle Growth Molar Mass and Molar Mass Distribution Particle Size Distribution Ingredients in Recipes Monomers Initiators Surfactants Others Emulsion Copolymerization Penultimate Unit Effect in Copolymerization Monomer Partitioning in Emulsion Polymerization Composition Drift in Emulsion Co‐ and Terpolymerization Ternary Emulsion Copolymerization Chemical Composition Distribution and Molar Mass Chemical Composition Distribution Process Strategies in Emulsion Copolymerization Constant Addition Strategy Controlled Composition Reactors Optimal Addition Profile Batch, Semi‐Batch, and Continuous Emulsion Polymerization Particle Morphologies Introduction to Particle Morphologies Core–Shell Morphologies Organic Cores Encapsulation of Inorganic Particles Hollow Particles Special Chemistry in Conventional Emulsion Polymerization Reactive Latices Crosslinking of Polymers by Low Molar Mass Crosslink Agents Crosslinking Between Polymers with Complementary Reactive Groups Reactive Surfactants Unconventional Emulsion Polymerization Unconventinal Free‐Radical Emulsion Polymerization Ionic Emulsion Polymerization Transition Metal Catalyzed Emulsion Polymerization Enzyme‐Catalyzed Emulsion Polymerization Concluding Remarks Applications Paints Paper Coatings Adhesives Biomedical and Pharmaceutical Applications Impact Modifiers Appendix I Appendix II

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“…Palladium complexes are known as a catalyst for various organic reactions, including Heck reaction and polymerization of norbornene . A few papers have reported CHO polymerization catalyzed by palladium complexes.…”

Section: Introductionmentioning

confidence: 99%

“…Palladium complexes are known as a catalyst for various organic reactions, including Heck reaction 20 and polymerization of norbornene. 21 A few papers have reported CHO polymerization catalyzed by palladium complexes. For example, Zhang et al 22 reported the polymerization of CHO in dichloromethane using Pd(CH 3 CON-(2-pyridyl) 2 ) (CH 3 CN) 2 2+ (PF −6 ) 2 as catalyst.…”

Section: Introductionmentioning

confidence: 99%

Solvent‐free ring‐opening polymerization of cyclohexene oxide catalyzed by palladium chloride

Chang

Cao

et al. 2018

Polymers for Advanced Techs

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In this study, we have for the first time demonstrated that palladium chloride (PdCl2) is an efficient catalyst for ring‐opening polymerization of cyclohexene oxide in a solvent‐free condition. The polymerization product was in atactic structure, and reaction conditions, such as reaction temperature, time, and catalyst amount, showed effects on polymerization conversion yield, turnover number, and number‐average molecular weight of the resulting poly(cyclohexene oxide). PdCl2 catalysis follows a cationic ring‐opening mechanism. The polymerization result is highly determined by the chemical structure of the monomers.

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First example of latices synthesis via oligomerization of norbornene in aqueous emulsions, catalyzed by palladium chloride

Cited by 31 publications

References 18 publications

The Vinyl Homopolymerization of Norbornene

The Vinyl Homopolymerization of Norbornene

Emulsion Polymerization

Solvent‐free ring‐opening polymerization of cyclohexene oxide catalyzed by palladium chloride

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