Organic geochemical
(TOC, pyrolysis, biomarker) and petrographic
(maceral analysis) investigations together with organic carbon isotope
studies were carried out to characterize in detail the depositional
environment, determine the organic matter type, and assess the hydrocarbon
production potential of three coal seams (KP1-upper, KM3-middle, and
KM2-lower) in the Soma (Manisa, Western Anatolia) coal field in Turkey.
The total organic carbon value of the upper coal seam ranged between
11.7 and 55.75%, the middle coal seam between 20.12 and 62.86%, and
the lower coal seam between 50.03 and 65.71%. Coals in all three seams
are characterized by low hydrogen index (HI) values (<151 mg HC/g
TOC), low bitumen index (BI) (<19 g HC/g TOC), and quality index
(QI) between 23 and 156 mg HC/g TOC. According to Rock-Eval pyrolysis
data, the organic matter type of the coals is type III kerogen. Huminite
reflectance, Tmax, and biomarker data (22
S
/22S+22R
(C
32
) sterane, ββ/(αα + ββ)
(C
29
) sterane, and MPI-1) indicate that the organic matter
is not thermally mature and that the Soma-Manisa coal has reached
the sub-bituminous rank. Rock-Eval data shows that coal is gas-prone
and has not reached the maturity threshold required for initial gas
production. The dominant maceral group is huminite while liptinite
and inertinite macerals have been found in minor amounts. Groundwater
index (GWI), vegetation index (VI), tissue preservation index (TPI),
and gelification index (GI) parameters indicate a transition from
limnic-limno-telmatic to limno-telmatic-telmatic environment from
the upper seam to the lower seam.
N
-Alkane distributions
show that paleoclimatic conditions have changed from KP1 to KM2. The
higher abundance of pristane compared to phytane and low C
35
/C
31
–C
35
homohopane index values demonstrate
that the coals were deposited in a suboxic–oxic environment.
The predominance of
n
-alkanes with generally high
carbon number, relative variable abundances of C
27
–C
28
–C
29
steranes, δ
13
C values,
C/N ratios, and very low gammacerane index indicate a terrestrial
ecosystem with nonmarine influence, although algae and microorganisms
also contributed to the biomass.