First structural confirmation of different geometrical isomers in the same crystal lattice: the crystal structure of benzoylacetonatocarbonyltriphenylphosphinerhodium(I)

A Novel 1:1 Co-Crystal of Bis(1,10-Phenanthroline)(1,10-Phenanthroline-5,6-Dione)Nickel(II) Hexafluorophosphate and Tris(1,10-Phenanthroline)Nickel(II) Hexafluorophosphate Complexes, [Ni(phen)2(phen-dione)] [Ni(phen)3] (PF6)4

“…To date, only a few co-crystal complexes, for example, of Cu(II), Cu(I), Rh(I), and Ln(III) have been reported [59][60][61][62][63]. Co-crystallization of two different molecules is a possible way of intentionally influencing the position of molecules in a crystal lattice and allows for the investigation of newly generated macroscopic properties.…”

Crystal structure of dichlorido bis(2-methylbenzothiazole-κ 1N)palladium( II) chloride, C16H14Cl2N2PdS2

“…the oxygen atom with sulphur atom to study the effect on coordination behaviour of these ligands [7][8][9][10]. However the cyclization process to form benzothiazoles often prevents the formation of these types of ligands [11][12][13].…”

N,N-Bis(diphenylphosphanyl)cyclobutanamine

“…Diphosphinoamine (PNP) and other P donor ligands (Muller et al, 2008;Purcell et al, 1995;Otto et al, 2005;Otto & Roodt, 2001) with various substituents on both the P and N atoms form part of ongoing research in different catalytic olefin transformation reactions such as hydroformylation (Haumann et al, 2004;Crous et al, 2005), metathesis (Booyens et al) methoxycarbonylation (Ferreira et al, 2007) and tetramerization (Cloete et al, 2011). In the title compound, C 29 H 29 NP 2 , Fig.1, all bond distances and angles fall within the range for similar complexes (Keat et al, 1981;Cotton et al, 1996;Fei et al, 2003;Cloete et al, 2008Cloete et al, , 2009Cloete et al, , 2010Engelbrecht et al, 2010aEngelbrecht et al, , 2010b.…”

“…For similar structures, see: Keat et al (1981); Cotton et al (1996); Fei et al (2003); Cloete et al (2008Cloete et al ( , 2009Cloete et al ( , 2010; Engelbrecht et al (2010a,b). For diphosphinoamine (PNP) and other P-donor ligands, see: Muller et al (2008); Purcell et al (1995); Otto & Roodt (2001); Otto et al (2005). For their use in catalytic olefin transformation reactions, see: Haumann et al (2004); Crous et al (2005); Booyens et al (2007); Cloete et al (2011); Ferreira et al (2007).…”