2024
DOI: 10.1021/acs.cgd.4c01052
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Flexible Ligands Constructed Metal–Organic Frameworks as Visual Test Paper for Fluorescent Detection

Qiao Han,
Shuai Liu,
Si-Qi Bao
et al.

Abstract: In this paper, four new metal−organic frameworks (MOFs) were synthesized by the solvothermal method based on two imidazolidyl flexible ligands, named, CUST-662−665, [Zn(pbbm)(HBTC)]•3H 2 O (CUST-662), [Cd 2 (pbbm) 2 (BTC)(NO 3 )• H 2 O]•2H 2 O (CUST-663), [Cd 3 (bbbm) 3 (BTC) 2 •4H 2 O]•3H 2 O (CUST-664), and [Zn 2 (bbbm) 2 (BTC)(HCOO)]•3H 2 O (CUST-665). All four MOFs with blue fluorescence show excellent performance in the detection of pollutants including Fe 3+ , Cr 2 O 72− , trinitrophenol (TNP), and tetra… Show more

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