This study employed a rotating packed bed (RPB) to enhance the absorption process of NO x and SO 2 into Na 2 SO 3 solution with the preoxidation by ozone. The absorption performance of NO x and SO 2 was evaluated in terms of removal efficiency (η R ) and overall volumetric mass transfer coefficient (K G a) under various operating conditions including O 3 /NO x molar ratio (MR), rotation speed of RPB (N), gas− liquid ratio (G/L), Na 2 SO 3 concentration (C Na 2 SO 3 ), inlet SO 2 concentration (C SO 2 ), solution pH, and oxygen concentration (C O 2 ). The effect laws of the operating conditions on the η R and K G a of both NO x and SO 2 have been obtained. The results showed that η R values of NO x and SO 2 can reach up to 90 and 99%, respectively. Therefore, this process with the advantages of high efficiency, small size, and simple process for simultaneous absorption NO x and SO 2 exhibits a wide application prospect in the field of flue gas purification.