Fluorescent silver nanoclusters (Ag NCs) in the metal–organic framework MIL-101(Fe) for the catalytic hydrogenation of 4-nitroaniline

Abstract

A fluorescent Ag nanocluster deposited iron based metal organic framework, Ag NC@MIL-101(Fe), was synthesized with significant stability and enhanced catalytic activity towards the heterogeneous reduction of 4-nitroaniline under green and ambient conditions.

Sandwich type polyoxometalates encapsulated into the mesoporous material: synthesis, characterization and catalytic application in the selective oxidation of sulfides

“…6b). 48 The X-ray diffraction pattern of the P 2 W 18 Ce 3 @MIL-101 nanocomposite is in good agreement with P 2 W 18 Sn 3 @MIL-101, thus conrming both polyoxotungstates have the same diffraction pattern (Fig. 6c).…”

Boosting Visible‐Light Photocatalytic Performance for CO2 Reduction via Hydroxylated Graphene Quantum Dots Sensitized MIL‐101(Fe)

“…[ 39 ] The characteristic peaks of MIL‐101(Fe) were confirmed by excellent agreement with the references reported previously. [ 36,42,43 ] The XRD patterns of the as‐synthesized GQD/MIL‐101 samples were shown in Figure 1b. It could be seen that the X‐ray diffraction peaks of G/M‐3%,G/M‐5% and G/M‐7% match well with the standard MIL‐101 (Fe) sample.…”

Ultrafine Silver Nanoparticles Embedded in Cyclodextrin Metal‐Organic Frameworks with GRGDS Functionalization to Promote Antibacterial and Wound Healing Application

“…[22] Other MOFs like iron-based MOF (MIL 101) (MIL stands for Material of Institut Lavoisier), zinc based MOF-5, MOF-177, zeolitic imidazolate frameworks, i.e., ZIF-8, and ZIF-90 have also been used to synthesize NPs confined within the crystal framework. [23][24][25] However, these MOF materials, used as templates, might possess drawbacks of potential health hazards in reason of the metals used for their formation. The synthesis process requires either high heat, pressure or radiation to undergo reduction of metal ions.…”

“…Spherically shaped Ag NPs of around 50 nm have been synthesized using Zn‐MOF . Other MOFs like iron‐based MOF (MIL 101) (MIL stands for Material of Institut Lavoisier), zinc based MOF‐5, MOF‐177, zeolitic imidazolate frameworks, i.e., ZIF‐8, and ZIF‐90 have also been used to synthesize NPs confined within the crystal framework . However, these MOF materials, used as templates, might possess drawbacks of potential health hazards in reason of the metals used for their formation.…”