Fluorinated acrylic monomer modified core-shell polyacrylate latex particles: Preparation, properties and characterizations

Zhang, Fuhao; Cheng, Jing; Yan, Zhangyin; Ge, Shengsong; Liu, Ping; Maganti, Srihari; Xu, Ben Bin; Mahmoud, Khaled H.; El‐Bahy, Zeinhom M.; Huang, Mina; Guo, Zhanhu

doi:10.1016/j.polymer.2022.124783

Cited by 20 publications

(6 citation statements)

References 67 publications

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“…(a) Comparing the thermal performance of S5 within the present study with other recently reported composites: S5 within the present study and WAIA2/Si 4 , 30 3%PDMS, 39 SMA‐8, 40 4:1, 41 R4152/SiO 2 ‐Ag, 14 2.0 wt%, 42 NAuZ‐2.0, 18 ZnO/acrylate film, 43 20%, 44 3 wt% AHPU/EB600, 45 5 wt% poly(VAEM‐co‐MMA), 46 WA/KH567 (5 wt%), 23 AT‐4, 27 F5 26 . (b) Differential scanning calorimetric curves of pure P(MMA/BA) and ZSR/P(MMA/BA) composite films.…”

Section: Resultssupporting

confidence: 51%

“…Comparing the thermal performance of S5 within the present study with other recently reported composites: S5 within the present study and WAIA2/Si 4 , 30 3% PDMS, 39 SMA-8, 40 4:1, 41 R4152/SiO 2 -Ag, 14 2.0 wt%, 42 NAuZ-2.0, 18 ZnO/acrylate film, 43 20%, 44 3 wt% AHPU/EB600, 45 5 wt% poly(VAEM-co-MMA), 46 WA/KH567 (5 wt%), 23 AT-4, 27 F5. 26 observed in uniformly heating at 200 C for 24 h. Pencil hardness, adhesion, and impact strength of unmodified acrylate significantly decreased after heating. On the contrary, ZSR/(P(MMA/BA)) showed no significant change with increasing ZSR content.…”

Section: Samplementioning

confidence: 92%

“…Besides, polyurethane is sensitive to moisture and prolonged immersion in water can cause the material to age and swell, reducing performance. The third method is organic fluorine modification, 26,27 because the C F bond energy of organic fluorine is much higher than that of the C C bond, and it has a unique low surface energy, which greatly enhances the hydrophobicity of the films. Therefore, the introduction of organic fluorine into the acrylate can effectively improve the deficiencies in heat resistance, water resistance, and oil repellency.…”

Section: Introductionmentioning

confidence: 99%

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High‐performance ZSR/P(MMA/BA) composites with enhanced thermal and excellent water resistance properties

Chen,

Wu,

et al. 2024

J of Applied Polymer Sci

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Acrylate had developed rapidly because of its excellent chemical resistance, high‐gloss surface, and weather resistance. However, the poor heat resistance of acrylate limited its application in coatings. To overcome this problem, an organic–inorganic hybrid polymer of zirconium silicone resin (ZSR)‐modified acrylate has been successfully synthesized by solution polymerization. The results indicated that the heat resistance of acrylate was significantly improved due to the SiOSi and SiOZr structures of ZSR and the increased cross‐linking density induced by ZSR. After the incorporation of ZSR, the decomposition temperatures of 5% of acrylate increased from 300.4 and 349.2°C. The performance of the ZSR/(P(MMA/BA)) showed no significant change in uniformly heating at 200°C for 24 h. The composite films showed hydrophobicity, with the contact angles increasing to more than 90°. The S4 sample displayed the outstanding comprehensive performance, that is, 5% weight loss at 341.3°C, water contact angle of 97.9°, elongation at break of 852%, and tensile strength of 9.9 MPa. The high‐performance heat resistant coating is a promising material for application in architecture, decoration, and mechanical equipment.

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Section: Resultssupporting

confidence: 51%

Section: Samplementioning

confidence: 92%

Section: Introductionmentioning

confidence: 99%

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High‐performance ZSR/P(MMA/BA) composites with enhanced thermal and excellent water resistance properties

Chen,

Wu,

et al. 2024

J of Applied Polymer Sci

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“…23 The core-shell structure of the colloidal particles enables the relatively hydrophobic CAPA3091 shell to form a hydrophobic skeleton inside the matrix to maintain mechanical properties during emulsion demulsication. [53][54][55] As the R value increases, material phase separation, hard segment proportion, and chemical crosslinking density all increase. These factors mitigate the decrease in mechanical properties caused by water increase.…”

Section: Performance Of Mwpu Materials In An Aqueous Environmentmentioning

confidence: 99%

Synthesis of completely solvent-free biomedical waterborne polyurethane with excellent mechanical property retention and satisfactory water absorption

Zhen,

Zhang,

Wang

et al. 2024

J. Mater. Chem. A

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“…Meanwhile, a small amount of siloxane was added to the core layer to effectively improve the hydrophobicity, crosslinking density, and aging resistance of latex films. Zhang et al synthesized core–shell latex particles via a semicontinuous emulsion polymerization using acrylate monomers as the main materials and octafluoropentyl methacrylate (OFPMA) as modified monomers, and the results showed that the hydrophobicity, thermal stability, and mechanical properties of polyacrylate emulsion were further improved. According to our previous research, the prepared CLPs ( T g = 25 °C) with film formation were successfully applied to textile printing using a screen-printing method, and the printed fabrics had excellent color fastness and a soft and hard feel.…”

Section: Introductionmentioning

confidence: 99%

Ink-Jet Printing of Colored Latex Inks with a “Soft” Core–“Hard” Shell Structure

Yang

Yin

Sheng

et al. 2023

ACS Appl. Polym. Mater.

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Colored latex particles (CLPs) as a novel colorant have been widely applied to salt-free dyeing and printing due to their adjustable composition, brilliant colors, excellent durability, and small particle size. In this paper, the effects of glass-transition temperatures (T g) on the filterability of CLP inks were first studied, and the results showed that the CLP inks can be successfully filtered and ejected when the T g’s of CLP inks exceeded 48 °C. Based on our previous research, CLP (T g = 25 °C)-printed fabrics had excellent color fastness and a soft hand feel, while a stiff hand feel occurred with the increase of the T g. Herein, the CLPs with a core–shell structure (CLP@PS) were designed using CLPs (T g = 25 °C) as a “soft” core for ensuring the color fastness of printed fabrics and PS as a “hard” core for ensuring excellent filterability of inks. Transmission electron microscopy and dynamic light scattering indicated that the prepared particles had an obvious core–shell structure, and the particle size was 96 nm. To balance the filterability of inks and color fastness of printed fabrics, the encapsulated thickness was optimized at 20 nm by adjusting the amounts of styrene (St) and 2,2′-azobis(2-methylpropionamidine) dihydrochloride (AIBA). The flow rate and filtration time of CLP@PS inks were 8.9 mL/s, and 11 s, respectively. Finally, the CLP@PS inks were applied to ink-jet printing of cotton fabric. Compared with pigment ink-jet printing, CLP@PS-printed fabrics had a softer hand feel and better rubbing and washing fastness.

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Fluorinated acrylic monomer modified core-shell polyacrylate latex particles: Preparation, properties and characterizations

Cited by 20 publications

References 67 publications

High‐performance ZSR/P(MMA/BA) composites with enhanced thermal and excellent water resistance properties

High‐performance ZSR/P(MMA/BA) composites with enhanced thermal and excellent water resistance properties

Synthesis of completely solvent-free biomedical waterborne polyurethane with excellent mechanical property retention and satisfactory water absorption

Ink-Jet Printing of Colored Latex Inks with a “Soft” Core–“Hard” Shell Structure

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