Fluorinated Organozinc Reagents

Abstract

Introduction Fluoroalkenylzinc Reagents Perfluoroaryl Zinc Reagents Fluorinated Allyl and Propargylzinc Reagents Perfluoroalkynylzinc Reagents Perfluoroalkylzinc Reagents Dialkoxyphosphinyldifluoromethylzinc Reagents Carboalkoxydifluoromethylenezinc Reagents

Advances in Transition Metal (Pd,Ni,Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-organometallics as Reaction Partners

“…Perfluorinated organometallics are an important class of coupling partners as fluorine can be easily introduced into the organic backbone via cross-coupling reactions 145,146. The Qing group prepared the fluorine containing alkylzinc reagent 10 from the corresponding alkyl bromide by the treatment with zinc dust in anhydrous DMF at ambient temperature 147.…”