2024
DOI: 10.1021/acsapm.4c01475
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Fluorine-Free Nonisocyanate Polyurethane Antismudge Coating Carrying 4,5-Epoxycyclohexane-1,2-dicarboxylic Acid Diglycidyl Ether Groups

Canqun Liu,
Zhenyong He,
Yiyang Liu
et al.

Abstract: Epoxycyclohexane-1,2-dicarboxylic acid diglycidyl ether cyclic carbonate (EDDC) was synthesized by chemical addition of carbon dioxide with 4,5-epoxycyclohexane-1,2-dicarboxylic acid diglycidylester (EDD) and then cross-linked with isophorondiamine (IPDA) and amino-modified poly-(dimethylsiloxane) (AMPDMS) to prepare a unique fluorine-free antismudge nonisocyanate polyurethane coating (NIPU). Notably, the specific surface energy of NIPU was affected dramatically by the AMPDMS component. When its content was 1.… Show more

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