2013
DOI: 10.2118/144179-pa
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Formation Damage Caused by Improper Mn3O4-Based Filter-Cake-Cleanup Treatments

Abstract: Summary Cleanup of filter cake is a difficult task and becomes more challenging when dealing with weighting materials [e.g., manganese tetraoxide (Mn3O4)]. Mn3O4 is a strong oxidizing agent and can be used as a catalyst because of its active phase, a nonstoichiometric Mn3O4 composed of an octahedral Mn2O3 phase and a tetrahedral MnO phase, which will result in complex interactions with most cleaning fluids. The reaction of selected organic acids and chelating agents with Mn3O4 particles as a fun… Show more

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Cited by 25 publications
(4 citation statements)
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“…Filter cake is intentionally formed to prevent the reservoir formation and minimize the damage. On the other hand, the filter cake must be efficiently cleaned after the drilling operation to enhance the productivity of the open-hole section and ensure good cementing quality for the cased sections. In general, the filter cake layer is classified according to the source of the solids that form the layer. It is mainly either the drilling fluid solid additives (e.g., weighting material of the drilling fluid, such as barite, calcite, ilmenite, manganese tetroxide, and others) or the formation solids (cuttings) that accumulate during the drilling operations, if not removed. From the removal perspectives, the filter cake is also be classified on the basis of the base of the drilling fluid. Chelating agent solutions, such as DTPA, EDTA, GLDA, and HEDTA, were very active in dissolving metal-containing materials that form the filter cake layer.…”
Section: Chelating Agents As Filter Cake Removersmentioning
confidence: 99%
“…Filter cake is intentionally formed to prevent the reservoir formation and minimize the damage. On the other hand, the filter cake must be efficiently cleaned after the drilling operation to enhance the productivity of the open-hole section and ensure good cementing quality for the cased sections. In general, the filter cake layer is classified according to the source of the solids that form the layer. It is mainly either the drilling fluid solid additives (e.g., weighting material of the drilling fluid, such as barite, calcite, ilmenite, manganese tetroxide, and others) or the formation solids (cuttings) that accumulate during the drilling operations, if not removed. From the removal perspectives, the filter cake is also be classified on the basis of the base of the drilling fluid. Chelating agent solutions, such as DTPA, EDTA, GLDA, and HEDTA, were very active in dissolving metal-containing materials that form the filter cake layer.…”
Section: Chelating Agents As Filter Cake Removersmentioning
confidence: 99%
“…The reaction of selected organic acids and chelating agents with Mn 3 O 4 particles as a function of time and temperature was studied [35]. Mn 3 O 4 is a strong oxidizing agent and can be used as a catalyst because of its active phase, a nonstoichiometric Mn 3 O 4 composed of an octahedral Mn 2 O 3 phase and a tetrahedral MnO phase, which will result in complex interactions with most cleaning fluids.…”
Section: Removal Of Manganese Tetraoxidementioning
confidence: 99%
“…The reaction of diethylene triamine pentaacetic acids, a chelate, with Mn 3 O 4 particles in a glass reactor produced manganese silicates at 100 and 140 • C [35]. Kinetic tests were conducted using a three-neck round-bottom flask.…”
Section: Removal Of Manganese Tetraoxidementioning
confidence: 99%
“…In addition, the weighing material account for almost 70–90% of the filter cake mineralogy 19 . Furthermore, the weighting material might damage the formation during the formation and removal process of the filter cake 36 , 37 , hence it is critical to add filtration agents to minimize the filtration to the formation. Many filtering agents have been developed and employed in the oil and gas sector throughout the years and despite the success stories for them.…”
Section: Introductionmentioning
confidence: 99%