Formation of shortened partially multiple bonds of transition metals with carbenoid compounds of heavy p elements of groups III–VII as a reason for the occurrence of the HSAB principle

Пасынский, А. А.

doi:10.1134/s1070328411100095

Russ J Coord Chem

2011

DOI: 10.1134/s1070328411100095

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Formation of shortened partially multiple bonds of transition metals with carbenoid compounds of heavy p elements of groups III–VII as a reason for the occurrence of the HSAB principle

А. А. Пасынский

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Cited by 10 publications

References 25 publications

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Synthesis and Reactivity of Bis(6‐diphenylphosphinoacenaphth‐5‐yl)ditelluride

Giang

Lork

Beckmann

2018

Zeitschrift anorg allge chemie

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The reduction of the previously known [(6‐Ph2P‐Ace‐5‐)Te]Cl with K‐selectride (K[sec‐Bu3BH]) provided the title compound (6‐Ph2P‐Ace‐5‐)2Te2 (1). The oxidation of 1 under aerobic conditions afforded the related (6‐Ph2P(O)‐Ace‐5‐)2Te2 (2). Alternatively, 2 was prepared by reduction of the previously known 6‐Ph2P(O)‐Ace‐5‐TeCl with K‐selectride. The reaction of 1 with [Cp(CO)2Fe]2 proceeded with cleavage of the Te–Te and Fe–Fe bonds with elimination of CO and gave rise to a racemic mixture of (6‐Ph2P‐Ace‐5‐)TeFe(CO)Cp (3), which contains pseudo‐tetrahedral Fe atoms in a chiral environment. Upon crystallization, the racemate most likely undergoes spontaneous resolution into a conglomerate of enantiopure crystals.

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Synthesis and Reactivity of Bis(6‐diphenylphosphinoacenaphth‐5‐yl)ditelluride

Giang

Lork

Beckmann

2018

Zeitschrift anorg allge chemie

View full text Add to dashboard Cite

show abstract

Synthesis and Molecular Structure of Redox Active Platinum–Bis(Telluroferrocenyl) Complex and its Chelated Rhenium-Chloro(Tricarbonyl) Derivative

et al. 2014

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Spatial variations and ecological risk assessment of heavy metals in surface sediments on the upper reaches of Hun River, Northeast China

Guo

2013

Environ Earth Sci

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Formation of shortened partially multiple bonds of transition metals with carbenoid compounds of heavy p elements of groups III–VII as a reason for the occurrence of the HSAB principle

Cited by 10 publications

References 25 publications

Synthesis and Reactivity of Bis(6‐diphenylphosphinoacenaphth‐5‐yl)ditelluride

Synthesis and Reactivity of Bis(6‐diphenylphosphinoacenaphth‐5‐yl)ditelluride

Synthesis and Molecular Structure of Redox Active Platinum–Bis(Telluroferrocenyl) Complex and its Chelated Rhenium-Chloro(Tricarbonyl) Derivative

Spatial variations and ecological risk assessment of heavy metals in surface sediments on the upper reaches of Hun River, Northeast China

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