Four new CuI/AgI-based coordination compounds containing 2-mercapto-5-methyl-1,3,4-thiadiazole: Synthesis, crystal structures and fluorescence properties

CuI/AgI‐containing coordination compounds as advanced catalysts for selective oxidation of styrene to benzaldehyde

“…The complexes derived from CuCl (or CuBr, AgNO 3 ) and Hmthd ligand were prepared solvothermally according to the literature by some of our authors. [43] All the chemicals were reagent grade and used without further purification. The samples were characterized by powder X-ray diffraction (PXRD) analysis in a scanning angle (2θ) range of 4 -40 at a scanning speed of 6 /min.…”

“…All four compounds were firstly synthesized by some of our authors very recently. [43] Two neutral Hmthd ligands interact with one {CuCl} moiety to form a mononuclear coordination complex of 1 (Figure S1a). Compound 2 is a two-dimensional layered structure constructed from anionic [CuBr(mthd)] 2 2À units and one-dimensional coplanar cationic {[Cu 2 (mthd)] + } n chains (Figure S1b,c).…”