Four-Phase Equilibrium Relations Including Clathrate Hydrate Phase in a Ternary System of Xenon, Benzene, and Water

Abstract

Thermodynamic stability boundaries of xenon (Xe) + benzene mixed hydrate system were measured in a temperature range of (274.1 to 284.4) K and pressure range up to 0.5 MPa. The four-phase equilibrium curve of structure-II hydrate (H sII ), aqueous (L w ), C 6 H 6 -rich liquid (L HC ), and gas (G) phases in the Xe+benzene mixed hydrate system intersects with the three-phase equilibrium curve (H sI +L w +G) in the structure-I simple Xe hydrate system. The slope of H sII +L w +L HC +G in the Xe +benzene mixed hydrate system changes around (283.00 ± 0.05) K and (0.420 ± 0.005) MPa. At temperatures above 283.00 K, the structure-II Xe+benzene mixed hydrate collapses and instead, the structure-I simple Xe hydrate is formed.