Handbook of Applied Solid State Spectroscopy
DOI: 10.1007/0-387-37590-2_9
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Fourier Transform Infrared Spectroscopy

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Cited by 33 publications
(19 citation statements)
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“…These energies are given in eV, and can be considered approximately similar to the respective LUMO and HOMO energies of complex 1 . 9 c ,38 As such, the LUMO of the complex is at −4.45 eV or 0.7 eV above gold, whereas the HOMO energy level is about 1.7 eV below (Fig. 8).…”
Section: Resultsmentioning
confidence: 89%
See 1 more Smart Citation
“…These energies are given in eV, and can be considered approximately similar to the respective LUMO and HOMO energies of complex 1 . 9 c ,38 As such, the LUMO of the complex is at −4.45 eV or 0.7 eV above gold, whereas the HOMO energy level is about 1.7 eV below (Fig. 8).…”
Section: Resultsmentioning
confidence: 89%
“…Therefore, knowing that the gold electrode displays Fermi levels at −5.1 eV below the vacuum level, 5,9 d ,37 we convert the reduction and oxidation potentials of complex 1 , obtained via cyclic voltammetry, to assess the solid-state energies associated with the frontier molecular orbitals of the molecule. The experimental potentials measured vs. Ag/AgCl are transformed into saturated calomel electrode potentials ( V SCE ), and then converted into the first electron affinity ( V a ) and first ionization energy ( V i ) of the molecule as respectively given by the Hipps and Armstrong models: 5,38 V a = 4.7 eV + E red 1/2 (SCE) V i = 4.7 eV + (1.7) E ox 1/2 (SCE)…”
Section: Resultsmentioning
confidence: 99%
“…FT-IR spectroscopy includes the absorption, emission, reflection, or photoacoustic spectrum achieved by Fourier transform of an optical interferogram. 166 In paper IV FT-IR spectra were measured with a PerkinElmer FTIR spectrometer in a range of 400-4000 cm -1 . (Paper III and IV).…”
Section: Fourier Transform Infrared Spectroscopymentioning
confidence: 99%
“…Compared to other types of characterization analysis, FTIR is quite popular. This characterization analysis is quite rapid, good in accuracy, and relatively sensitive (Jaggi and Vij, 2006).…”
Section: Introductionmentioning
confidence: 99%