Franz Fehér (1903–1991)

Baudler, M.

doi:10.1002/(sici)1099-0682(199812)1998:12<2089::aid-ejic2089>3.0.co;2-9

Cited by 3 publications

(2 citation statements)

References 151 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Thereby, a mixture of hydridosilanes is formed and subsequently separated by high vacuum distillation, following the so‐called Stock‐procedure . Later, the work on hydridosilanes was continued by Fehér et al . They published numerous papers on hydridosilanes including physicochemical and spectroscopic characterization .…”

Section: Introductionmentioning

confidence: 99%

“…Thereby, a mixture of hydridosilanes is formed and subsequently separated by high vacuum distillation, following the so-called Stock-procedure. [27] Later, the work on hydridosilanes was continued by Fehér et al [28] They published numerous papers on hydridosilanes including physicochemical and spectroscopic characterization. [29][30][31][32][33][34] The potential of energy-rich silicon hydrides for chemical propulsion of aircraft vehicles has been investigated by Hidding and others.…”

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Syntheses and Molecular Structures of Liquid Pyrophoric Hydridosilanes

et al. 2020

View full text Add to dashboard Cite

Trisilane, isotetrasilane, neopentasilane, and cyclohexasilane have been prepared in gram scale. In‐situ cryo crystallization of these pyrophoric liquids in sealed capillaries on the diffractometer allows access to the single crystal structures of these compounds. Structural parameters are discussed and compared to gas‐phase electron diffraction structures from literature and with the results from quantum chemical calculations. Significantly higher packing indices are found for the silanes compared to the corresponding alkanes. Radiation with ultraviolet light (365 nm) and parallel ESR (EPR) measurement shows that cyclohexasilane is easily split into radicals, which subsequently leads to the formation of branched and chain‐like oligomers. The other compounds form no radicals under these conditions. NMR spectra of all four compounds have been recorded.

show abstract

Section: Introductionmentioning

confidence: 99%