Frequency-Dependent Dewetting of Thin Liquid Films Using External ac Electric Field

Abstract

The stability of thin liquid films on a surface can be controlled by using external stimuli, such as an electric field, temperature, or light, by manipulating the total excess free energy of the system. It has been previously shown that thin lubricating films on slippery surfaces can be destabilized via the spinodal mechanism using an external electric field, which returns to the original stable configuration upon the electric field. However, the role of the frequency of the applied ac electric field is not clear, which is the main topic of study in this report. When an ac electric field of fixed voltage and varying frequency is applied across thin lubricating films of slippery surfaces, a different dewetting behavior is observed. Characteristic length and time scales of dewetting depend strongly on the frequency of the applied voltage, which is primarily due to the change in the dielectric behavior of the lubricating fluid. In addition, the interplay of various time scales involved in the dewetting process also depends on the frequency.