Frequency up-shift in the stimulated thermal scattering under two-photon absorption in liquids and colloids of metal nanoparticles

Smetanin, I. V.; Ерохин, А. И.; Baranov, A. N.

doi:10.1088/1555-6611/aabf6f

Cited by 1 publication

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“…In our previous reports [ 13 , 14 ], we have reconsidered the experimental results on measured zero spectral shift of 2PA SRMS in nanocolloids which has been reported in [ 5 , 12 ]. Our measurements have been undertaken in Ag nanoparticle colloidal solutions in toluene and hexane and reveal the appearance of non-zero anti-Stokes spectral shifts in backscattered signal for both these colloids.…”

Section: Introductionmentioning

confidence: 99%

Stimulated Thermal Scattering in Two-Photon Absorbing Nanocolloids under Laser Radiation of Nanosecond-to-Picosecond Pulse Widths

et al. 2022

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Recent discoveries in nonlinear optical properties of nanoparticle colloids make actual the challenge to lower the energy threshold of phase conjugation and move it into the domain of shorter pulse widths. A novel effect of the stimulated Rayleigh-Mie scattering (SRMS) in two-photon absorbing nanocolloids is considered as a promising answer to this challenge. We report the results of experimental and theoretical study of the two-photon-assisted SRMS in Ag and ZnO nanocolloids in the nanosecond-to-picosecond pulse width domain. For 12 ns 0.527 μm laser pulses, the four-wave mixing SRMS scheme provides lasing and amplification of backscattered anti-Stokes signal in Ag nanocolloids in toluene at the threshold 0.2 mJ and the spectral shifts up to 150 MHz. For 100 ps 0.532 μm pulses, we observed for the first time efficient (over 50% in signal-to-pump ratio of pulse energies) SRMS backscattering of the anti-Stokes signal in Ag nanocolloids in toluene and predominantly Stokes signal in ZnO nanocolloids in water, with the spectral shifts up to 0.25 cm−1. We develop the first order-in-perturbation model of the four-wave mixing two-photon absorption-assisted SRMS process which shows that at nanosecond pulses, amplification is predominantly due to the thermal-induced coherent oscillations of polarization while the slow temperature wave acts also as a dynamic spatial grating which provides a self-induced optical cavity inside the interaction region. At a picosecond pulse width, according to our model, the spectral overlap between pump and signal pulses results in formation of only the dynamic spatial temperature grating, and we succeeded at recovering the linear growth of the spectral shift with the pump power near the threshold.

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